... For the auto-acceleration regime, the experimental data correspond to the kinetic equation wt = k [ P ] 1/2 t [ IO 4 ] - 1/2 t [TMB]0, where wt is the accumulation rate of the meriquinoid product (P) of TMB oxida- 4 ]t tion and [P]t and [ IO are the concentrations of product P and periodate, respectively, at time t. A radical chain mechanism was proposed; the mechanism explains the experimental kinetic equation and complies with the observed inhibiting effect of metal ions (Zn, Cd) in this reaction....
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Ссылки http://analyt.chem.msu.ru/kinetics/papers/ZhAKh%20mechanism%202006.pdf -- 172.3 Кб -- 25.09.2008 Похожие документы
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Ссылки http://oc.cs.msu.ru/eroven/NEW%20Rovenskaya%20IIASA%20conference%20presentation.pdf -- 734.1 Кб -- 06.11.2012 Похожие документы
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Ссылки http://storage.bioinf.fbb.msu.ru/~roman/bmc_genom2_2013.pdf -- 1974.9 Кб -- 15.12.2013 Похожие документы
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