Äîêóìåíò âçÿò èç êýøà ïîèñêîâîé ìàøèíû. Àäðåñ îðèãèíàëüíîãî äîêóìåíòà : http://www.inorg.chem.msu.ru/sis/r450/
Äàòà èçìåíåíèÿ: Mon Feb 8 18:51:46 2016
Äàòà èíäåêñèðîâàíèÿ: Sun Apr 10 00:18:30 2016
Êîäèðîâêà: Windows-1251
Prof. Dolgikh group. Department of Chemistry, MSU
Russian version

GROUP OF THE DESIGN AND FINE SYNTHESIS OF INORGANIC PHASES WITH UNUSUAL ELECTROPHYSICAL PROPERTIES

Inorganic Synthesis Laboratory, Inorganic chemistry division, Department of Chemistry, MSU

Dolgikh V.A.
Group leader Dr.Sc., Prof.
Dolgikh V.A.
Phone: 007-(495)-939-3504
email dolgikh *

GROUP STAFF

 
Ardashnikova. E.I.

Ph.D. Associate Prof.
Ardashnikova E.I.
ard*

Berdonosov P.S.

Ph.D. Associate Prof.
Berdonosov P.S.
berdonosov*

Charkin D.O.

Ph.D. S Associate Prof.
Charkin D.O.
charkin*

 




 

POSTGRADUATE STUDENTS

 

Elena Kuznetsova

Elena S. Kuznetcova

(Department of Chemistry) supervised by PSB & VAD

e.kuznetsova*

 

 


Position Vacant

Contact V.A. Dolgikh

STUDENTS

Akhmad
Akmad Yu. Akhrorov

Department of Materials Science, supervised by PSB


 

Artur Urmanov
Igor V. Plokhikh

 Department of Chemistry, supervised by DCH

Gorbachev A
Anatolii V. Gorbachev

Department of Materials Science, supervised by DCH

Ignat'ev Jane
Ivan A. Ignat'ev

Department of Materials Sciences, supervised by DCH

Zakharov Alex
Alex Yu. Zakharov

Department of Chemistry, supervised by DCH

Moskalenko Egor
Konstantin E. Gur'yanov

Department of Materials Sciences, supervised by DCH

 

 

   

          Dissertations  & Diploma projects

           PICTURES

Working in glovebox

Group Photo (approx end of 1992)
Group Photo (2004) Group Photo (May 2005) Group Photo (May 2006) Vladimir A. Prituzhalov PhD council pictures (2008)
Group Photo (June 2010) B.V. Egorova diploma (June 2011) St Andrews visitors in June 2013 May - June 2014

GROUP ALUMNI

 RESEARCH ACTIVITIES

Determination of the correlations between composition, structure ferroelectric, ion-conducting and nonlinear optic properties of crystals as the scientific base for design and synthesis of inorganic compounds with required properties.

MAIN OBJECTS UNDER INVESTIGATION IN THE RECENT YEARS

Complex tellurites and selenites of bismuth and rare earth elements (REE), complex oxohalogenides and oxochalkogenides.

Large family of layered oxyhalogeniges of Bi(REE)-Te belonging to a new type was discovered and investigated. This family has a high percentage of compounds with noncentrosymmetric structures. Among them the phases were found having high nonlinear optic parameters and unique combination of piezoelectric and pyroelectric parameters advantageous for pyroelectric applications.
The correlations between the composition and the structure were determined for the phases in this group.
With the help of planned heterovalent substitution of Bi or REE atoms in their fluorite-like oxofluorides, new anion-conducting phases with wide homogenity regions were obtained. The correlation between nonstoichiometry and transport characteristics of these solid solutions were determined.
Current interests include design, synthesis, crystallographic and SHG characterization of new layered and inorganic open framework phases.

Research highlights
BiOCuSe
BiOCuSe unit cell
First Bi compound with LnOTX (Ln - lanthanide, Bi; T = Cu, Ag; X = S, Se, Te, T = Fe, Ni, X = P, As) structure
α--BiSeO3Cl

First Selenate(IV) chloride of Bi (III) with NCS structure

 
SrTeO3
SrTeO<sub>3</sub> structure and SHG signal
Ferroelectric with unusual properties and complex structure
MNd10(SeO3)12Cl8 (M=Ca, Sr)
SrTeO<sub>3</sub> structure and SHG signal
First Alkaline Earths representatives of M11(SeO3)12Xx phase family
   

COLLABORATIONS

Prof. P. Lightfoot  in the School of Chemistry  at the University of St Andrews, UK

Prof. Dr. rer. nat. Michael Ruck Anorganische Chemie der TU Dresden,  Germany

Professor Alain Tressaud Research Director at ICMCB-CNRS, University Bordeaux 1 (France)

CURRENT PROJECTS:

RFBR 14-03-00604 Design and targeted synthesis of novel hybrid inorganic phases - salt inclusion solids Supervisor V.A. Dolgikh

FINISHED PROJECTS:

RFBR 11-03-00776 The synthesis concept and targeted synthesis of inorganic crystal phases with structures based on open framework 2011-2013 Supervisor V.A. Dolgikh
RFBR Royal Society UK 12-03-92604-KO-a A Crystal-chemical Approach to New Frustrated Magnets 2012-2013 Supervisor V.A. Dolgikh
 
RFBR
12-03-00665 Directed synthesis of low dimensional d-metal complex selenite-halides as possible frustrated magnets 2012-2014 Supervisor P.S. Berdonosov

RFBR 09-03-00799 Synthesis of the complex s-/d-metals,Bi/d-metal selenates(IV) halides and tellurates(IV) halides with noncentrosymmetrical structures 2009-2011 Supervisor P.S. Berdonosov
RFBR 09-03-01064 Development and application of modular approach to design and synthesis of complex inorganic layered perovskites 2009-2011 Supervisor D.O. Charkin

RFBR 08-03-00548 The crystal chemistry approach to the design and targeted synthesis of new open-framework inorganic phases 2008-2010 Supervisor V.A. Dolgikh

PUBLICATIONS

Some papers from XX century      
2000 2001 2002 2003
2004 2005 2006 2007
2008 2009 2010 2011
       

2015

Dmitri O.Charkin, Igor V. Plokhikh, Alexey N. Kuznetsov, Sergey M. Kazakov  BaFAlSi and BaFAlGe: First transition metal-free LaOAgS-type fluoride tetrelides  // Journal of Alloys and Compounds 627 (2015) 451-454  

Lewis J. Downie, Elena I. Ardashnikova, Chiu C. Tang, Alexandre N. Vasiliev, Peter S. Berdonosov, Valery A. Dolgikh, Mark A. de Vries and Philip Lightfoot  Novel S = 1/2 Kagome Lattice Materials: Cs2TiCu3F12 and Rb2TiCu3F12  // Crystals 2015, 5(2), 226-243; doi:10.3390/cryst5020226 

Dmitri O. Charkin, Cameron Black, Lewis J. Downie, Dmitry E. Sklovsky, Peter S. Berdonosov, Andrei V. Olenev, Wuzong Zhou, Philip Lightfoot, Valery A. Dolgikh Cs7Sm11[TeO3]12Cl16 and Rb7Nd11[TeO3]12Br16, the new tellurite halides of the tetragonal Rb6LiNd11[SeO3]12Cl16 structure type // Journal of Solid State Chemistry (2015) doi:10.1016/j.jssc.2015.08.043  

Dmitri O. Charkin, Victor S. Akinfiev, Anastasia M. Alekseeva, Maria Batuk, Artem M. Abakumov and Sergey M. Kazakova Synthesis and cation distribution in the new bismuth oxyhalides with the Sillen-Aurivillius intergrowth structures // Dalton Trans., 2015,44, 20568-20576 doi:10.1039/C5DT02620B  

2014

Dmitri O. Charkin, Arthur V. Urmanov, Igor V. Plokhikh, Alexander D. Korshunov, Alexey N. Kuznetsov, Sergey M. Kazakov Synthesis and crystal structures of novel LaOAgS-type alkaline earth - Zinc, manganese, and cadmium fluoride pnictides  // Journal of Alloys and Compounds 2014, Vol. 585, Pages 644-649  

V.A.Sidorov, A.E.Petrova, P.S.Berdonosov, V.A.Dolgikh and S.M.Stishov Comparative study of helimagnets MnSi and Cu2OSeO3 at high pressures// PHYSICAL REVIEW B 89 (2014) 100403(R)

Ivan D. Kharitonov, Dmitri O. Charkin, Peter S. Berdonosov, Cameron Black, Lewis J. Downie, Philip Lightfoot and Valery A. Dolgikh Rare-earth cadmium tellurite chlorides with a new structural type exhibiting [Ln12(TeO3)12] slabs alternating with CdCl6 octahedral layers // European Journal of Inorganic Chemistry  Volume 2014, Issue 19, pages 3140- 3146, July 2014 DOI:10.1002/ejic.201402177

Peter S. Berdonosov, Elena S. Kuznetsova, Valery A. Dolgikh, Alexei V. Sobolev, Igor A. Presniakov, Andrei V. Olenev, Badiur Rahaman, Tanusri Saha-Dasgupta, Konstantin V. Zakharov, Elena A. Zvereva,  Olga S. Volkova, and Alexander N. Vasiliev  Crystal Structure, Physical Properties, and Electronic and Magnetic Structure of the Spin S = 5/2 Zigzag Chain Compound  Bi2Fe(SeO3)2OCl3 // Inorg. Chem 53 (2014) 5830−5838 DOI 10.1021/ic500706f

L.J. Downie, C. Black, E.I .Ardashnikova, C.C. Tang,, A.N. Vasiliev, A.N. Golovanov, P.S. Berdonosov, V.A.Dolgikh and P. Lightfoot Structural phase transitions in the kagome lattice based materials Cs2−xRbxSnCu3F12 (x =0, 0.5, 1.0, 1.5) // CrystEngComm, 2014, 16, 7419-7425 DOI: 10.1039/c4ce00788c

Dmitri O. Charkin, Roman Demchyna, Yurii Prots, Horst Borrmann, Ulrich Burkhardt, Ulrich Schwarz, Walter Schnelle, Igor V. Plokhikh, Sergey M. Kazakov, Artem M. Abakumov, Dmitry Batuk, Valery Yu. Verchenko, Alexander A. Tsirlin, Caroline Curfs, Yuri Grin ,and Andrei V. Shevelkov Two New Arsenides, Eu7Cu44As23 and Sr7Cu44As23, With a New Filled Variety of the BaHg11  Structure //  Inorg. Chem., Article ASAP  DOI: 10.1021/ic5017615

K. V. Zakharov, E. A. Zvereva, P. S. Berdonosov, E. S. Kuznetsova, V. A. Dolgikh, L. Clark, C. Black, P. Lightfoot, W. Kockelmann, Z. V. Pchelkina, S. V. Streltsov, O. S. Volkova, and A. N. Vasiliev Thermodynamic properties, electron spin resonance, and underlying spin model in Cu3Y(SeO3)2O2Cl //  Phys. Rev. B 90, 214417 DOI: 10.1103/PhysRevB.90.214417

2013

Peter S. Berdonosov, Lev Akselrud, Yurii Prots, Artem M. Abakumov, Philippe F. Smet, Dirk Poelman, Gustaaf Van Tendeloo and Valery A. Dolgikh Cs7Nd11(SeO3)12Cl16 - the first non-centrosymmetric structure among alkaline metal lanthanide selenite halides  // Inorg. Chem., 52(2013),pp. 3611−3619  

Peter S.Berdonosov, Oleg Janson, Andrey V. Olenev, Sergey V. Krivovichev, Helge Rosner, Valery A. Dolgikh, Alexander A. Tsirlin Crystal structures and variable magnetism of PbCu2(XO3)2Cl2 with X= Se, Te // DaltonTrans., 2013, 42, 9547 -9554  

Â. À. Ïðèòóæàëîâ, Å. È. Àðäàøíèêîâà, À. Ì. Àáàêóìîâ, Â. À. Äîëãèõ ÍÎÂÛÉ ÀÍÈÎÍÏÐÎÂÎÄßÙÈÉ ÔËÞÎÐÈÒÎÏÎÄÎÁÍÛÉ ÒÂÅÐÄÛÉ ÐÀÑÒÂÎÐ Bi1 - xTex(O,F)2 + δ (0.28 < x < 0.43)   ÑÈÑÒÅÌÅ BiF3-BiÎF-TeO2 // ÆÓÐÍÀË ÍÅÎÐÃÀÍÈ×ÅÑÊÎÉ ÕÈÌÈÈ, 2013, òîì 58, ? 7, ñ. 851-857 

2012

S.Shenawi-Khalil, D.O. Charkin,  V.Uvarov,  A.Goaz,  I.Popov,  V.A.Dolgikh,  Y.Sasson A new bismuth potassium nitrate oxide, Bi1.7K0.9O2(NO3)2: synthesis, structure, thermal behavior, and photocatalytic properties // Solid State Sciences 14(2012) 159-165

P.S. Berdonosov, A.V. Olenev, V.A. Dolgikh Lead (II) Selenite Halides Pb3(SeO3)2X2 (X = Br, I):  Synthesis and Crystal Structure // Crystallography Reports, 2012, Vol. 57  No. 2, pp. 200-204Ï.Ñ. Áåðäîíîñîâ. À.Â. Îëåíåâ, ,Â.À. Äîëãèõ ÑÅËÅÍÈÒ ÃÀËÎÃÅÍÈÄÛ ÑÂÈÍÖÀ (II) Pb3(SeO3)2X2 (X = Br, I): ÑÈÍÒÅÇ È ÊÐÈÑÒÀËËÈ×ÅÑÊÀß ÑÒÐÓÊÒÓÐÀ // ÊÐÈÑÒÀËËÎÃÐÀÔÈß, 2012, òîì 57, ? 2, 248-252.

Dmitri O. Charkin, Arthur V. Urmanov, Sergey M. Kazakov Preparation and crystal structures of novel LaOAgS-type copper and silver fluoride chalcogenides // Journal of Alloys and Compounds 516 (2012) 134-138

Charkin D.O., Lebedev D.N., Kazakov S.M.  Synthesis and Crystal Structure of Layered Oxyhalides BaPbBi3Nb2O11X (X= Cl, Br, I) // Russian Journal of Inorganic Chemistry, òîì 57, ? 7, ñ. 917-922

Dmitri O.Charkin, DmitriN.Lebedev, SergeyM.Kazakov Multiple cation and anion substitutions into the structures of Bi2WO6 and PbBi3WO8Cl // Journal of Alloys and Compounds 536(2012)155-160

Peter S. Berdonosov, Andrei V. Olenev, Maria A. Kirsanova, Julia B. Lebed, Valery A. Dolgikh Bi6(SeO3)3O5Br2: A New Bismuth Oxo-Selenite Bromide // Journal of Solid State Chemistry 2012, Vol. 196, pp. 232-237

Dmitri O.Charkin, Arthur V. Urmanov, Sergey M. Kazakov, Dmitri Batuk, Artem M. Abakumov, Stephan Knoner, Elena Gati, Bernd Wolf, Michael Lang, Andrey V .Shevelkov, Gustaaf Van Tendeloo, Evgeni V. Antipov  Synthesis, Crystal Structure, Transport and Magnetic Properties of Novel Ternary Copper Phosphides A2Cu6P5 (A = Sr ,Eu)and Eu Cu4P3  // Inorg. Chem., 2012, 51 (16), pp 8948-8955 

 

Note All our e-mails are in inorg.chem.msu.ru domain. E-mail should be nickname@inorg.chem.msu.ru Back to top
 

  The Moscow METRO map. The nearest to MSU metro station is "Universitet" (red line).  
Moscow


Last updated 08.02.2016