Key Reviews
Organometallic Chemistry and Mechanisms
Biomimetics
Organometallic and Inorganic Biochemistry
 
 

Key Reviews

A. D. Ryabov "Cyclopalladated complexes in organic synthesis", Synthesis, 1985(3), 233-252.

A. D. Ryabov "Mechanisms of intramolecular activation of C-H bonds in transition metal complexes", Chem. Rev., 1990, 90(2), 403-424.

A. D. Ryabov "The biochemical reactions of organometallics with enzymes and proteins", Angew. Chem., Int. Ed. Engl., 1991, 30(8), 931-941.

Organometallic Chemistry and Mechanisms

R. A. Gossage, A. D. Ryabov, A. L. Spek, D. J. Stufkens, J. A. M. van Beek, R. van Eldik, G. van Koten, 'Models for the Initial Stages of Oxidative Addition. Synthesis, Characterization and Mechanistic Investigation h¹-I₂ Organometallic 'Pincer' Complexes of the Platinum Group Metals.  The X-Ray Crystal Structures of [PtI(C₆H₃{CH₂NMe₂}2-2,6)(h¹-I₂)], exo-meso-[Pt(h¹-I₃)(h¹-I₂)(C₆H₃{CH₂NMe₂}2-2,6)] and [PdI(C₆H₃{CH₂NMe₂}2-2,6)]*(I₂)₂'J. Am. Chem. Soc. 1999, 121(11), 2488-2497.

A. D. Ryabov, I. M. Panyashkina, V. A. Polyakov, J. A. K. Howard, L. G. Kuz'mina, M. S. Datt, C. Sacht, "An Access to Planar Chirality through Cycloplatination of Dimethylaminomethylferrocene by cis-[PtCl₂(SOMeAr)₂] (Ar = Phenyl and p-Tolyl)', Organometallics, 1998, 17(16), 3615-3618.
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W. Ferstl, I. K. Sakodinskaya, N. Beydoun-Sutter, G. Le Borgne, M. Pfeffer, A. D. Ryabov, 'Mechanism of Alkyne Insertion into the Ru-C Bonds of Orthoruthenated Compounds Featuring Similarity of the Ru(II) and Pd(II) Reactions', Organometallics, 1997, 16(3), 411-418.
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A.D. Ryabov, G.M. Kazankov, I.M. Panyashkina, O.V. Grozovsky, O.G. Dyachenko, V.A. Polykov and L.G. Kuz`mina. "Cycloplatination of aryl nad ferrocenyl oximes by cis-[PtCl₂(OSMe₂)₂] affording execter platinum(II) and unexpected platinum(IV) products". J. Chem. Soc., Dalton Trans., 1997, 4385-4391.
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L. Alexandrova, O.G. Dyachenko, G.M. Kazankov, V.A. Polyakov, P.V. Samuleev, E. Sansores, and A.D. Ryabov. "Mechanism of Biologically Relevant Deoxygenation of Dimethyl Sulfoxide Coupled with Pt(II) to Pt(IV) Oxidation of Orthoplatinated Oximes.  Synthetic, Kinetic, Electrochemical, X-Ray Structural, and Density Functional Study". J. Am. Chem. Soc. 2000, 122, 5189-5200.
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A.D. Ryabov, I.M. Panyashkina, G.M. Kazankov, V.A. Polyakov, L.G. Kuz`mina. "Complexes cis-[PdCl2(OSMeR)2] (R=Me, Ph, and C6H4Me-4) in attempted asymmetric cyclometalation of dimethylaminomethylferrocene". J. Organomet. Chem. 2000, 601, 51-56.
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V.A. Polykov, M.I. Nelen, N. Nazarpack-Kandlousy, A.D. Ryabov, and A.V. Eliseev. "Imine exchange in O-aryl O-alkyl amines as a base reaction for aqueous `dynamic` combinatorial libraries. A kinetic and thermodynamic study". J. Phus. Org. Chem. 1999, 12, 357-363.
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G. Wagner, A.J.L. Pombeiro, Y.N. Kukushkin, T.B. Pakhomova, A.D.Ryabov, V.Yu. Kukushkin. "Iminoacylation. 2. Addition of alkylated hydroxylamines via oxygen to platinum(IV)-bound nitriles". Inorg. Chim. Acta 1999, 292, 272-275.
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Biomimetics
 

A. D. Ryabov, G. M. Kazankov, S. A. Kurzeev, P. V. Samuleev, V. A. Polyakov.' Enantioselective cleavage of activated amino acid esters promoted by chiral palladacycles'. Inorg. Chim. Acta. 1998, 280(1/2), 57-61.
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E. V. Krooglyak, G. M. Kazankov, S. A. Kurzeev, V. A. Polyakov, A. N. Semenov, A. D. Ryabov. "Targeting of Pallada- and Platinacycles to the N-((tert-Butyloxy)carbonyl)-L-Methionine p-Nitrophenyl Ester for Promotion of the Ester Cleavage". Inorg. Chem.,  1996, 35(13), 4804-4806.
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S.A. Kurzeev, G.M. Kazankov, A.D. Ryabov. "Increased catalytic activity of primary amine palladacycles in hydrolysis of N-tBOC-S-methionine p-nitrophenyl ester". Inorg. Chim. Acta 2000, 305, 1-6.
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G.M. Kazankov, V.S. Sergeeva, E.N. Efremenko, L. Alexandrova, S.D. Varfolomeev and A.D. Ryabov. "Highly Efficient Degradation of Thiophosphate Pesticides Catalyzed by Platinum and Palladium Aryl Oxime Metallacycles". Angew. Chem. Int. Ed. 2000, 39 (17), 3117-3119.
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G.M. Kazankov, O.G. Dyachenko, A.V. Nemukhin and A.D. Ryabov. "The nature of biomimetically relevant rate enhancement of hydrolysis in a coordination sphere of square-planar metal complexes suggested by an X-ray structural stugy of a,b-h,g-[Pt{o-C₆H₄C(Me)=NOC(=O)Me}(мю-Cl)]₂". Mendeleev Commun. Electronic Version, 1997, 4, 127-168.
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Organometallic and Inorganic Biochemistry

E. S. Ryabova, V. N. Goral, E. Csoregi, B. Mattiasson, and A. D. Ryabov, 'Coordinative Approach to Mediated Electron Transfer: Ruthenium Complexed to Native Glucose Oxidase', Angew. Chem. Int. Ed. Engl. 1999, 38(6) 804-807.
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A. D. Ryabov, V. N. Goral, L. Gorton, and E. Csoregi 'Electrochemically and Catalytically Active Reconstituted Horseradish Peroxidase with Ferrocene-Modified Hemin and Artificial Binding Site', Chem. Eur. J., 1999, 5(3), 961-967.
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A. D. Ryabov, Y. N. Firsova, A. Yu. Ershov, I. A. Dementiev 'Spectrophotometric kinetic study and analytical implications of the glucose oxidase-catalyzed reduction of the [M^III(LL)₂Cl₂ ]+ complexes by D-glucose (M = Os and Ru, LL = 2,2'-bipyridine and 1,10-phenanthroline type ligands)', J. Biol. Inorg. Chem., 1999, 4(2) 182-190.
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A. D. Ryabov, Y. N. Firsova, V. N. Goral, E. S. Ryabova, A. N. Shevelkova, L. L. Troitskaya, T. V. Demeschik, V. I. Sokolov, "Enantioselectivity in Enzyme-Catalyzed Electron Transfer To and From Planar Chiral Organometallic Compounds ". Chem. Eur. J. 1998, 4(5), 806-813.
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A.D. Ryabov, V.S. Kurova, V.N. Goral, M.D. Reshetova, J. Razumiene, R. Simkus, and V. Laurinavicius. "p-Ferrocenylaniline and p-Ferrocenylphenol: Promising Materials for Analytical Biochemistry and Bioelectrochemistry". Chem. Mater. 1999, 11, 600-604.
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V.N. Goral, E. Csoregi, B. Mattiasson and A.D. Ryabov. "Complexation of ruthenium with glucose oxidase modified by 4-pyridineacetic and 4-imidazoleacetic acids". Mendeleev Commun. Electronic Version, 1999, 5, 171-212.
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A.D. Ryabov, V.N. Goral, E.V. Ivanova, M.D. Reshetova, A. Hradsky, B. Bildstein. "Linear free-energy relationships and inverted Marcus region in the horseradish peroxidase-catalyzed oxidation of ferrocenes by hydrogen peroxide". J. Organomet. Chem. 1999, 589, 85-91.
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E.S. Ryabova, E. Csoregi, A.D. Ryabov. "Influence of biologically relevant ligands on oxidation of reduced glucose by electrochemically generated [Ru^III(bpy)₂XY] complexes". J. Mol. Cat. B: Enzymatic. 2000, 593, 1-7.
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A.D. Ryabov, V.N. Goral. "Steady-state kinetics, micellar effects, and the mechanism of peroxidase-catalyzed oxidation of n-alkylferrocenes by hydrogen peroxide". JBIC, 1997, 2:182-190.
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