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V. A. Durov, A. P. Moscalets
Method of recursive
sequences in associated liquids theory
Abstract
A new method based on recursive sequences
(RS) is developed to calculate differential and integral characteristics of
supramolecular organization, as well as dielectric properties of associated
liquids in the framework of quasi-chemical model of non-ideal associated
solution (QCNAS). In case of chain association the comparison of RS-method with
earlier developed matrix technique is performed. The RS-method is consistent
with matrix-based technique in detailed description of structure and properties
of aggregates, and moreover can be extended to models of branched (for
instance, tree-like) supramolecular structure of liquids.
Copyright (C) Chemistry Dept., Moscow State University, 2002
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