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PECULIARITIES OF CHEMICAL COMPOSITION OF KLYUCHEVSKOY VOLCANO MELTS INSIGHT FROM MELT INCLUSIONS STUDY IN OLIVINES Mironov N.L.1,2, Portnyagin M.V.2, Pletchov P.Yu.1 1 - Geological department of Moscow State University. 2 - Vernadsky Institute of geochemistry and analytical chemistry RAS e-mail: nikita_mir@rambler.ru key words: olivines, melt inclusions, Klyuchevskoy volcano, basalts, melts. In order to characterize composition and evolution of parental melts of Kluchevskoy volcano, melt inclusions in olivine phenocrysts (Fo91-67) were studied. The olivines were picked from well dated lava samples of old cones Bulochka and Luchitskogo (2500-4000 y.a.), Ochki (1500-2000 y.a.) and of historic eruptions Tuyla (1932 y.), Apakhonchich (1946), Bylinkinoy (1951), Vernadskogo (1953) and Piipa (1966). Samples represent all geochemical varieties of Kluchevskoy volcano rocks: Bulochka and Luchitskogo lavas (MgO=11.2-12.1 wt.%) are high magnesian basalts, Ochki and Tuyla lavas (MgO=8.7-8.8 wt.%) are magnesian basalts, Apakhonchich, Bylinkinoy, Vernadskogo and Piipa lavas (MgO=4.4-5.9 wt.%, Al2O3=16.6-18.1 wt.%) are high alumina basalts (Fig.1,2) (rock types as in [1]).The data obtained provide comprehensive information about melts existed at Kluchevskoy volcano over the recent 4000 years of its volcanic activity. Partially recrystallised melt inclusions (most of melt inclusions studied) were experimentally rehomogenised. For this purpose heating stage with visual control of Sobolev-Slutsky construction [2] was used. The heating occured in atmosphere of pure He under atmospheric pressure. The inclusions were partially homogenized (melt + fluid phase) and quenched. Glasses of such inclusions and glasses of naturally quenched melt inclusions were analyzed by microprobe. The peculiarity of the melt inclusion compositions is low FeO content. We suggest this is due to the process of Fe-loss from inclusions after their entrapment. In order to recover the initial melt compositions, special calculation method developed by L. Danyushevsky [3] was used. This method allows to take into account the effect of Fe-loss and restore initial melt composition. Initial FeO content in melt was assumed to be 8.5 wt.% This value was taken from the average FeO content of Klyuchevskoy volcano rocks. It is important to note that unlike other oxides FeO content is rather constant in different types of Klyuchevskoy volcano rocks. This makes our assumption acceptable for all melts studied. The most of the melts obtained from the melt inclusions composition show significantly lower SiO2 and higher CaO, Al2O3 compared to the composition of host rocks at given MgO (Fig.1,2)
Fig.1 Composition of melts (m) and rocks (r) of Klyuchevskoy volcano. Pre-historic eruptions (age 1500-4000 years): 1-Luchitskogo, 2-Bulochka, 3Ochki. Rocks-all Klyuchevskoy rocks.
59 57 55
Roc ks 1-r 1-m 2-r 2-m 3-r 3-m

Fig.2 Composition of melts (m) Klyuchevskoy volcano. Historic 1932): 1-Tuyla, 2-Apakhonchich, Vernadskogo, 5-Piipa. Rocks rocks.
59 57 55
Roc ks 5-m 1-m 1-r 2-m 2-r

and rocks (r) of eruptions (after 3-Bylinkinoy, 4all Klyuchevskoy
3-m 3,4,5-r 4-m

SiO

2

53 51 49 47 45 2 4 6 8 10 12 MgO 14

SiO

2

53 51 49 47 45 2 4 6 8 10 12 MgO 14

1


21 20 19 18

21 20 19 18

16 15 14 13 12 2 4 6 8 10 12 MgO 14

Al2O

Al2O

17

17 16 15 14 13 12 2
14 13 12

3

3

4

6

8

10

12 Mg O 14

18 16 14 12 10 8 6 4 2 4 6 8 10 12 MgO 14

11 10

CaO

CaO

9 8 7 6 5 4 2 4 6 8 10 12 Mg O 14

Large statistics of melt compositions (more than 270) and their representativity for entire interval of crystallization gives a good reason to suppose that there were no parental melts in nature similar in composition to Klyuchevskoy volcano rocks. Melt inclusions, trapped by olivines on the early stages of crystallization provide true information about the composition of such melts. Rocks compositions on the contrary differ from melts due to complex processes of fractionation and are determined by various proportions of phenocrysts in evolved ground mass. Alternative explanation of melts and rocks compositional discrepancy could be exceptionally selective entrapment of melt inclusions by olivine phenocrysts. It means that there were trapped only those melts which were quite different from rocks. However, none example of such a process was published to date and possible reasons for such a selectivity are not clear. The data obtained showing the difference in composition of parental melts and rocks give a good reason to overview the existing models of Klyuchevskoy volcano rocks formation [1, 4, 5] This work was supported by RFBR grants 02-05-06482, 01-05-06152, 00-05-64384 and by RAS grant of 1999 308 References cited. [1] Ariskin A.A.; Barmina G.S.; Ozerov A.Y.; Nielsen R.L. (1995) Genesis of high alumina basalts from Klyuchevskoy volcano. Petrology., v.3, n.5, p.449-472. [2] Sobolev A.V., Slutskii A.B. (1984) Composition and crystallization conditions of the initial melt of the Siberian meimechites in relation to the general problem of ultrabasic magmas. Soviet Geology and Geophysics, v.25, n.12, p. 93-104. [3] Danyushevsky L.V., Della-Pasqua F.N., Sokolov S. (2000) Re-equilibration of melt inclusions trapped by magnesian olivine phenocrysts from subduction-related magmas: petrological implications. Contributions to Mineralogy and Petrology, v.138, p. 68-83. [4] Khubunaya S.A., Bogoyavlenskiy S.O., Novgorodtseva T.Y. and Okrugina A.I. (1994) The mineralogy of the Klyuchevskoi magnesian basalts depicting the fractionation in the magma chamber. Volcanology and Seismology., v.15, n.3, p.315-338. [5] Ozerov A.Y. (2000) The evolution of high-alumina basalts of the Klyuchevskoy volcano, Kamchatka, Russia, based on microprobe analyses of mineral inclusions. Journal of Volcanology and Geothermal Research, v. 95, p.65­79.

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