Äîêóìåíò âçÿò èç êýøà ïîèñêîâîé ìàøèíû. Àäðåñ îðèãèíàëüíîãî äîêóìåíòà : http://geo.web.ru/pubd/2012/08/31/0001186529/alferyeva.pdf Äàòà èçìåíåíèÿ: Fri Aug 31 19:04:03 2012 Äàòà èíäåêñèðîâàíèÿ: Mon Feb 4 10:25:48 2013 Êîäèðîâêà:

- - Si-Al-Na-Li-H-F-O 25.00.04 ­ ,

-

-2012


()
: - - , - , : , , ( )

:

«5» 2012 . 14:30 . . 415 501.001.62 .. : 119991, , -1, , , .

.. ( ., 27).

«3» 2012 .

- .. 2


- , , - . ­ Si-Al-Na-Li--F-O =800° =1, - . . . 1) . . 2) . 3) , : , . 4) - . . Si-Al-Na-Li--F-O =800° =1 . . . , , . - . , , , , - . , . . .
3


. . ; . . « » . ... . 72 . . (.). - (. ), (, ), - - ( , ), (, ), - (. ). . 1. Si-Al-Na-Li-H-F-O 800° 1 , , -, , , . . 2. . , . 3. - . . . 16 . ,
4


: 33 IGC, 2008 (, ) Hutton VI, 2007 (, ). « » (), , «» (), , ( ), , : (), ( , ), ( , ). . , 7 , . 43 10 . 140 . 136 . , . .., .., .. . .., .., , . 1 . , , , . , , , ., ­ . . , , . , , , . . , , , , , , ., , , . , , . ­ .
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. . . (,1933; Smith, 1948; , 1960; , 1960; , 1966; , 1971; , , 1978; , , 1981; ., 2005). - (, 1957; , , 1958; ., 1967; , , 1977; , , 1970; , , 1970, 1981; .,1990; .. . 1977; , , 1978; ., 2005; Dolejs & Baker, 2007 .). . (2005) . 2. . =800°, =1 . SiO2, NaAlO2, AlF3, NaF, LiF, Al2SiO5. Ta Nb 1.% . . 10% . «Jeol ISM-6480LV» . Si, Al, Na, F - , . . ( ) F 0,05%, Na, Al, Si ­ 0,02%. ±10 .% 1 .%; ±5 .% 5 .%; ±2 .% 5 .%. , . . . () . , (Thomas, 2000, 2006). 1. : (. ) ( , . ).
6


1-2 . 800 130-160°. , , . , , . 3. . ( 1- ) =800° =1 : , , , , (. 1). .

.

.

.

.

1. : ) , ) , ) , ) .

: ­
7


, ­ , ­ . , . , , .. . (3-10 ), , , . , 1-3 . , (. 1). 50 500 . , ( . 2005), ., , (. 2). , , , . ( ) . , , () 5 2 (. 1). , , . , .

.

.

2. , . ) , ) () . ­ , , ., ­ . 8


1. , 100% , , , . .

. 526* 530* 531* 594 597 598 599 621 622 641* 696*

L L LF L LF L LF L LF L LF L LF L LF L LF L LF L LF L LF Cry L LF Cry L Cry L L L L L L

Si

Al

Na

Li . . . . .

F 10.6 15.0 66.5 10.6 72.5 6.8 60.7 11.5 61.9 15.8 56.0 34.5 63.1 15.0 62.5 18.7 63.6 28.0 62.0 7.1 62.7 12.3 67.6 63.2 5.2 51.3 55.9 6.3 60.7 6 6 7 6 6 5 .6 .2 .7 .3 .8 .6

O 58.3 53.1 5.4 56.8 3.0 61.7 4.1 57.6 5.0 53.9 4.7 35.8 10.0 50.3 8.1 47.1 5.0 41.0 7.9 61.8 8.4 57.8 3.2 . 62.8 4.1 1.5 63.6 1.2 6 6 6 6 6 6 2 2 2 2 3 3 .8 .0 .1 .5 .2 .8

527* 593 596 571 573 690* 691* 698* 699*

L + LF 22.3 4.7 4.0 17.3 7.3 7.3 1.1 9.8 17.2 17.1 8.4 7.1 0.3 9.1 15.0 22.8 5.1 3.1 0.5 0.9 9.0 20.9 4.3 20.9 5.1 4.5 0.4 1.5 9.7 17.6 4.2 18.2 6.3 5.0 0.8 1.1 9.2 14.4 14.6 11.1 9.3 9.3 2.4 9.8 14.7 17.8 6.5 10.5 1.1 7.4 21.0 16.5 7.2 10.4 0.7 7.6 23.1 13.7 9.4 8.0 1.8 12.7 15.6 20.5 7.5 3.2 2.7 11.2 15.0 L + Cry ± LF ± Qtz 21.3 5.1 3.5 1.1 10.2 17.9 . 10.4 26.3 22.1 4.7 4.2 1.0 0.8 12.9 26.6 4.2 . 9.5 29.7 3.4 21.3 5.0 2.6 1.2 0.1 10.2 24.5 3.3 L + Toz ± Qtz 22.3 5.6 2.7 22.9 5.9 3.0 23.7 4.6 2.1 22.6 5.6 3.1 23.1 5.0 1.8 24.5 4.3 1.9
9

. . . . . . . . . . . . .

. . . . . .


1.

. 529*



Si

Al

Na

Li

F 23.6 28.4 24.3 21.3

O 45.8 41.4 45.1 47.3

L 11.8 . 528* L 11.7 . 693* L 15.3 . 694* L 16.2 . : * - ,

L + Cor 11.5 7.3 11.2 7.3 7.3 8.0 7.7 7.5

; . ­ ; . ­ . : L ­ , LF ­ , Cry ­ .

­ (LLF). (. 1). - (. 3), Ka=(Na+Li)/Al 0,7 1,4. , .. : . Al/Na 20/80 40/60 (. 1). =L/LF 0,1 0,7, .. . . . 6 .% 23 .% 34 .% 11 .% (.% Si+Al+Na+F+O). P ­ . . , , . . .
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3. SiO2-AlO1,5-NaO0,5-SiF4-AlF3-NaF Si-Al-Na ( .% Si+Al+Na) =800° =1. : , ­ , ( - , - , ). , : 1- ; 2- ; 3- , 4- .

. 3,4 .% (. 1). . , 0,4. 4 .% ­ . . Li 0,1-0,3, L-Cry. ­ . . . :


, ­ . Si=22-25 .%, Al=4-6 .%, Na =2-3 .%. 2- . , . , (. 4). . 1-2 20 . - . , , , . , , ( 3 .%) . , , - .

4. . ( ) ( - ). - ­ . 12


, , . . (.2). =TaL/CTaLF 3,8 6,6. 1,4 ­ 1,7. , , . , . (. 5). , .
2. = /C , - 20 .
L LF



Ta , , .% .% Kp 594 1.8 0.5 597 1.6 0.2 598 1.3 0.2
L LF

Nb , , .% .% Kp 3.8 1.3 0.8 6.4 1.1 0.8 6.6 1.1 0.7
L LF

1.7 1.4 1.7

( ., 2009) ­ 130 280, ­ 40 110. . ­ . , : ­ ­ . . , Ta/Nb. , . 6, Ta/Nb , , ­ .

13


C

Ta(Nb)

L

2,0 1,8 1,6 1,4 1,2 1,0 0,8 60 65 70 75 80

C

SiO2

L

-T a -Nb 3 4 5 6 7 5. 8 ,

, . .%.
CTaL/C
L Nb

1,6 1,5 1,4 1,3 1,2 1,1 1 0,9 0,8 0,7 0,6 60 65 70 75 CSiO2L, 80 .%

-1 -2 -3

6. , : 1 ­ (=800°), 2 3 ­ ( ., 2009) 850 750° . 14


4. ( 3- ) =800° =1 : 1) .., 2004, (Reyf et al., 2001), (, 2001) (E.V.Badanina et al., 2004) (F.G.Reyf, et al., 2000), (Thomas et al., 2005.), . (Haapala et al., 1997.), - (R.Thomas, 1997), - (Lenharo et al., 2003); 2) - .. (2004) .. (1977); - (), ( ., 1971); 3) (Bailey, 1980; Pauly & Bailey, 1999; Goodenough et al., 2000), (Horbe et al., 1991; Lenharo et al., 2003; Minuzzi O.R.R. et al., 2008), (Jacobson, 1958; Borley et al., 1976; Kinnaird, Bowden, 1985), , ( ., 1991), , - ( ., 1988; ., 2006). . ( , . ) - (, ; , ; , .). Li-F : F, H2O, CO2, Li, Rb, Cs, W, Mo, Sn, Bi, Be, Hf, Ge, Ga, Tl, Ta, Nb Ti, Fe, Mn, Mg, Ca, Sr, Ba, Zr, REE, Y, Cu, V, Ni, Co . , , . : 1) . , . 2) , . , , . 3) - . . (1-3%)
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. , , . .. (1977) - ­ . .. . (Reyf et al., 2000) , . ( , ) , - 21 % . (, 1981, 1989) : 1) (). . , , 0,1 3 -5 .%. 2) -. , , . - 8-10%. 3) , (, 1981) . , , , , , , , .. . , . , . . . 7 - / , . . () ( . 2005), () ­ . , : , , . - , .
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A

0.8

12341.0

0.9

1 a= K

0.0
.

0.1
0.8

0.2

0.3

0.9

1 a= K
1.0

0.0
.

0.1

0.2

0.3

7 SiO2-AlO1,5NaO0,5-SiF4-AlF3-NaF Si-Al-Na ( .% Si+Al+Na), =800° =1 - . ) , ) . . . 18. 17


. 7: , ­ , ( - , , ). 1-4 ­ : 1- (, 2002; , 1975; , 1971; Lenharo, 2002; , 2006; Pichavant & Manning, 1984; ., 1987; Sviridenko, 1994; , 2004), 2- (, 1991; , 2004), 3- (Thomas, 1997, 2000; Badanina, 2004; , 1996; , 1991; Reyf, 2000), 4- .

. , . . , . , . . . , , - / . : . , , , -, . , , 150 , ­ 140 170 . 70% , 18% , 7% (Pauly, Bailey, 1999). - - , , 0,5 . (, , 1998). , , . (, ), , , , , (Na2LiAlF6)
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( , 3, , 1999). () (, , 1962), . (, ) (Kearns, 1995). -- - (, ) (Landes, 1935). . , , . , , , . , ­ . : , , , . , , ­ , , . , , , . . 25 . . , . , , , , -, , ( , .). , , . ( ., 2005; ., 2008) ­ ( ., 2011). . , -, .
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, , . (, 2003; , , 2008) () II . , , 100% , . , , . . , . 80-90% . . , , , ( ., ). ­ . , . , . , . . , LiF . 1,6 .%, ­ 8,6 .% (E.V.Badanina et al., 2004). .. , Li-F 4 .%, ­ 6 .% (F.G.Reyf, et al., 2000). 3 30 .% 1,9 6,4 .% . «» , 55 .% 3 .% (R.Thomas, et al., 2005). () : 0.4-0.6 .%.
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19 .% (C.Johnston, et al., 1992). , (C.Johnston, et al., 1992). - (6-8 .%). Si-Al-Na-Li-F-H2O 800° , , , 3 .%. , 5 .% . , «» 15-18 .% . SiO2 - F, , .
20 F, w t% 18 16 14 12 10 8 6 4 2 0 40 45 50 55 60 65 70 75 SiO2, w t%

-1 -5

-2 -6

-3 -7

-4

8. , , . : 1-3: , 1) =800°, 2) =800°, 3) =700°; 4 -7: - 4) (homas, 2000), 5) (homas, 1997), 6) (, 1996), 7) (homas, 2005) 21


. . . - . - , , . . . , , Ta/Nb . , , . .
1. .. X , «» / . . .. , .. . ( ) -- .: . .. , 2003. http://lomonosov-msu.ru/2003/Alfereva_J_O.doc.pdf 2. .., .., .. / VIII « ». . .: , 2007, 3, . 136-139. 3. Zaraysky G.P., Alfereva J.O., Udoratina O.V. Geochemical features of the tantalum deposit in Eastern Transbaikalia Etyka /Sixth International Hutton Symposium. Origin of granites and related rocks. Abstract. Stellenbosch, South Africa. 2007. P. 232-233. 4. . . , XIV , «» ( ) -- .: . .. , 2007: http://lomonosov-msu.ru/archive/Lomonosov_2007/06.htm 5. .., .., .. =800 H2O=1000 - « » 1(26)2008 ISSN 1819 ­ 6586 URL: http://www.scgis.ru/russian/cp1251/h_dgggms/1-2008/informbul-1_2008/magm-44.pdf 6. Alferyeva Y.O., Gramenitskiy E.N., Shchekina T.I. Liquid immiscibility in the fluorine saturated model granite system and the influence of lithium on phase equilibriums /33 International Geological Congress. Abstract. Oslo, Norway. 2008. Published on CD-ROM. 7. .., .., .., .. I II Si-Al-Na-K-Li-H-O .4 2008 6, . 26-31.

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8. .., .., .. - - 1(27)2009 , - -2009 URL: http://www.scgis.ru/russian/cp1251/h_dgggms/1-2009/informbul-1_2009/ct.pdf 9. .. Si-Al-Na-Li-F-H2O =800° = : , , 2.-.: - , 2009. . 3-8. 10. .., ., .. , 2009. : : http://geo.web.ru/pubd//2009/04/15/0001182162/25.pdf 11. .., .., .., .. . XI c . : , 2010. .2. . 362-363. 12. .., .., .. Si-Al-Na-Li-F-H2O 800°C 1 XVI . . : , 2010. . 133-135. 13. ., .., .. , 800° 1 - 2010. "". : http://geo.web.ru/db/msg.html?mid=1183766&uri=01.html 14. .., .., .. . . 2011. 7. . 1-16. 15. .., . . , . . , . . , , , 2011, 3, NZ6103, doi:10.2205/2011NZ000233. 16. .., .., .. , SiO2-Al2O3-Na2O-K2O-Li2O-H2O-F . , .-2012. . . . 2012. .100. 17. .., ..,. . : // . .

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