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-
.. , .. , . . , . . , .. .. , ..




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- Au

- Cu

0.05 0.05 0.02 Cu2+ pH=2.9

- Cu


- ?
.. ..
Cu6%Ag7% 60min Cu6%Ag7% 30min

37

38

39

, 2



NH NH2 NH2 NH2 NH2 OOC OOC OOC OOC Cu _+ H
2+

NH Cu
2+

NH Cu COO

NH
2+

COO

OOC

OOC

Metal
Cu (2+)
Co (2+) Ni (2+) Fe (2+) Ag (+)

Sorption,
wt., %

15

60

27
20 20 6 22

, ,


, -
­ 40%, 0.1 ­ 0.3 23


H2O \/\/ e- aq, .OH, +H3O, H2, .H . OH + CH3CH2OH CH3.CHOH + H2O n+ + en+

+ R (n-

.

aq



(n-1)+ 1)+

... Me0

+ R+


Reflection of silver nanoparticles

Reflection of copper nanoparticles

180 ,
Ag 7% Cu 6% 45 27 15 33 38 44

Dose irradiation 700 kGy

Dose irradiation 200 kGy

2.5%Ag 6%Cu
44 46 48

Ag 2,6% Cu 7% Ag 1,2% Cu 10%
Reflection of silver nanoparticles Reflection of copper nanoparticles

36

38

40

42

Angle 2 teta

Dose 400 kGy Dose 200 kGy Dose 100 kGy 35 40 Angle 2 teta 45

240

1.2%Ag 10%Cu

320

Me0 + Me+ Men+m Me(nnob)0 + Me(nob)+ Me(nnob)+ + Me(nob)0 Me(nnob)0 + Me (nob)0 Me(nnob)Me(nob) Me(nnob)n+m + Me(nnob)+ (Me(nnob)mMe (nob))

n+

( 1) ( 2) (3)




1.2%Ag 10%Cu

480 320 240 160



80





­
36,5 37,0 37,5 38,0 38,5 39,0 39,5

2


1.2%Ag 10%Cu

Me(nnob)0 + Me(nob)+ Me(nnob)+ + Me(nob)
Me(nnob)
n+ m

0
n+

(1)
(2)

+ Me(nnob)+ (Me(nnob)mMe (nob))


1 %A 5%Cu

u , , , , 38.159

Au 17.78 1 13.12 7 12.83 1

: 80 -

: 160 17.165

: 320

480 ­ 180

20.533

: 480 12.311




-. . , , . .





1) Vladimir I. Feldman, Alexey A. Zezin, Sergey S. Abramchuk, Elena A. Zezina. X-ray Induced Formation of Metal Nanoparticles from Interpolyelectrolyte Complexes with Copper and Silver Ions: the Radiation-Chemical Contrast // Journal of Physical Chemistry 2013 C, V.117, PP. 7286-7293 2) Aye Bakar, Olgun Guven, Alexey A. Zezin, Vladimir I. Feldman.Controlling the size and distribution of copper nanoparticles in double and triple polymer metal complexes by Xray irradiation // Radiation Physics and Chemistry Volume 94, January 2014, PP. 62­65

3) Dmitry V. Pergushov, Alexey A. Zezin, Alexander B. Zezin and Axel H.E. Muller. Advanced Functional Structures Based on Interpolyelectrolyte complexes// Adv Polym Sci, 2014 V.255: PP.173­226 DOI: 10.1007/12_2012_182,