Документ взят из кэша поисковой машины. Адрес оригинального документа : http://electr003.chem.msu.ru/kuznetsov/seminar1.pdf Дата изменения: Sun Mar 14 13:04:34 2010 Дата индексирования: Mon Oct 1 20:25:33 2012 Кодировка:

­ II.
: «» , ; ; ; .

: ; , , ; .

, ;


, 2003-2009 .. .. .. .. .. .. .. .. () R.Buchner (Regensburg Univ) W.R.Fawcett (Univ. california, Davis)


: - ....
(« »); ; : - ; - .

E

OHP

Reactant
''

: ; ( ) ; « ».

.


: I (), : (), (, , ) : - - -



: , // «» I: ; , «»: , ; ( !) : k , ,



- - ? ( !) - ? - ; -

«» I: ; ,


«» I: ; ,

? « » ()



( )/( «»)

: , !

= -1, -10, -25 /
2

( )/( )


2,5

(: )

2,0
EDTA

1 2 3 4 5

I,A

1,5

1,0

0,5
rEDTA

0,0 0,0 ­ - -0,5 -1,0 -1,5

E,V(SCE)



«» I: ; , -«» - « »



[PtCl4]2-


?

!

440 420 400 380 360 340 320

- / - -

s, mN/m

-

X(EG), % = 0 2 5 10 20 40 60 80 100

300 -0,2

0,0

0,2

0,4

0,6

0,8

1,0

1,2

1,4

1,6

-E, V (vs SCE)


?

-:

NaCl
140 130 120 110
-1

-

-

, 10 m S mol

100 90 80 70 60 50 40 30 20 10 0 0.0 0.2 0.4 0.6
-1 -1

1 2 3 4 5 6 7 8 9 10 11 experimental

-4

2

1,2

1,0

-

0,8

D/D
0.8 1.0

0

0,6

1/, mPa s

0,4

0,2

­ -

0,0 0,0 0,2 0,4 0,6 0,8 1,0

0/


-: ...


... ( ­ !)

: - ,

«» : -


Cr -:

, ­


-;
7 6 5 4 3 2 1 0 -0.4 -0.6 -0.8 -1.0 -1.2 -1.4 -1.6 -1.8 -2.0 -2.2

X(EG), % 0 10 20 30 40 50 60 70

i, mkA

E, V (vs SCE)




­ -
2.5 2.0 1.5

-1, V

I 1.0
0.5 0.0 -0.5 -1.0 -1.5 -2.0 -10 0 10 20

-0 -0 -0 -0 -0

.3 .4 .5 .6 .7

30

40

50

60

70

80

X(EG), %


(~) ­ -
2.0 1.5 1.0

-1, V

I

0.5 0.0 -0.5 -1.0 -1.5

-

0 0 0 0 0

.3 .4 .5 .6 .7

20

40

60

80

100

120

1, ps


: Frumkin correction

1932-33 1949

.., . . 1961


, ... , ... ...

: ..... .


.....

« » -


Christmas lecture in MSU

"Phenomenological theory of love"




-
( ) (k)(x,t), (k) g(k)(x,r)

(r)=0+(r)





E(k)(r,t)

, . ( ), .








, «» , .


: ( ) (1) , , ; (2) , ; (3) , ; (4) , , . , 1. .: , . 2. ..: .


Alexander Kuznetsov Prize for Theoretical Electrochemistry The Kuznetsov Prize is awarded every two years to a living individual who has made groundbreaking contribution to the theory of electrochemical phenomena, which explained/predicted an experimental discovery, or laid grounds to a new area of research. Call for nominations The Prize will be attributed for the first time in 2010, then each second year. Nominations are invited. They should be sent to the ISE Office not later than May 1st, 2010, and be in accordance with the award rules. Forms for the submission of applications may be found in the Society web site. .................. The winner will be announced at the ISE website not later than June 15th, 2010. The award will be presented at the 61st Annual ISE Meeting in Nice, France, in 2010, where the winner will give a lecture at a symposium sponsored or co-sponsored by ISE Division 7.