On the Structure and Dielectric Properties of Cyclohexanone-4-Methylcyclohexanol Mixture

Russian J. Phys. Chem., v. 71(3), 412-417 (1997),
translated into English from Zh. Fiz. Khim., v. 71(3), 450-454 (1997)

ABSTRACT. The analysis of dielectric properties and investigation of the supermolecular ordering in cyclohexanone - 4-methylcyclohexanol mixture was performed in a wide temperature and a whole concentration intervals. Equations for calculating of static permittivity (dipole correlation factor) of this mixture with the complex type of supramolecular association of molecules of alcohol, solvated by polar ketone molecules, have been derived. The thermodynamic and structural characteristics of the association and solvation was founded. An unified description of molecular nature of dielectric properties of a mixture in terms of generalized quasi-chemical models on the molecular-structural level was demonstrated.

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