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Lokteva E.S. , Simagina V.N. , Golubina E.V. , Stojanova I.V. , Lunin V.V.
Kinetika I katalys, N 6, (2000).
Abstract. In the presence of 0,5-5% Pd supported on carbonic material "Sibunit" in flow-type reactor at 150-230 C hydrodechlorination of CCl4 is accompanied with C1- C5 hydrocarbons formation. The main products are methane, C2, C3 and C4 hydrocarbons fractions and trace amount of C5. Products content didn't depends on the reaction conditions. Catalysts were stable; conversion of CCl4 was more then 90%. Non-selective formation of linear and branched hydrocarbons proves radical reaction mechanism.