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R. A. Gazzayeva, A. D. Tsargasov, A. N. Fedotov, S. S. Mochalov
The behavior of the cyclopropyl
phenyl sulfide and phenoxycyclopropane in the reaction with nitrous acid
Abstract
The
behavior of the cyclopropyl phenyl sulfide and phenoxycyclopropane in the
nitrosation reaction was studied. Cyclopropyl phenyl sulfide was found to
convert quantitatively to cyclopropyl phenyl sulfoxide under the action of
nitrous acid formed in situ. Under the same conditions
phenoxycyclopropane undergo transformation to 5-phenoxyisoxasoline
(nitrophenols are formed as side products in this reaction).
Copyright (C) Chemistry Dept., Moscow State University, 2002
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