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APPLIED PHYSICS LETTERS 97, 261908 2010

Surface-plasmon-induced enhancement of magneto-optical Kerr effect in all-nickel subwavelength nanogratings
A. A. Grunin, A. G. Zhdanov, A. A. Ezhov, E. A. Ganshina, and A. A. Fedyanina
Faculty of Physics, Lomonosov Moscow State University, 119991 Moscow, Russia

Received 10 October 2010; accepted 9 December 2010; published online 30 December 2010 Enhancement of transversal magneto-optical Kerr effect TKE is controlled experimentally in magnetoplasmonic subwavelength nanogratings made of nickel films by resonant excitation of surface plasmon-polaritons SPPs . Almost one order of magnitude increase of the TKE value is observed in the spectral range of Wood's anomaly corresponding to the fulfillment of the phase-matching conditions for SPP excitation. © 2010 American Institute of Physics. doi:10.1063/1.3533260 Recent achievements in optoelectronics and photonics require development of magnetophotonic microdevices intended for controlling the magneto-optical response at the microscale and submicroscale. One of the ways for enhancing the magneto-optical response is magnetophotonic crystals MPCs ,1 which are photonic crystals fabricated from transparent magnetic materials. Being initially realized as one-dimensional 1D photonic crystals, MPCs are extended now for all dimensionalities utilizing either microcavity-type enhancement of multiple reflectance interference or modification of the light dispersion law at the photonic-band gap edge.2­5 Practical realization of magnetophotonic devices based on MPCs requires magnetic materials with low absorption that ensures considerable photonic-band gap effect. Examples of such materials are dielectric ferrite-garnets of different compositions, but many of magnetic materials with high magnetic responses are metals with large absorption in visible and near infrared spectral regions. In metals, the only possibility to realize the effects analogous to photonic-band gap is the excitation of surface plasmon-polaritons SPPs in planar periodically nanostructured metal films which are called plasmonic or SPP-crystals.6 Dispersion law of SPPs becomes modified as a function of metal profile, and many effects in propagation of SPPs analogous to electromagnetic waves in photonic crystals--such as guiding, spatial localization, and anomalous slowing--can be observed. SPPcrystals are generally fabricated from noble metals because of large SPP propagation length. Strong modification of magneto-optical response near plasmonic resonances was discussed theoretically in Refs. 7­9. Magneto-optical Kerr effect MOKE enhancement was observed in magnetic materials impregnated with metallic nanoparticles due to local plasmon resonances.10­12 Recently, enhancement of MOKE was observed in metallic multilayer films by SPP excitation in the Kretschmann scheme.12­15 In this letter, both approaches of plasmonic and magnetophotonic crystals are combined for realization of a scheme of magneto-optical Kerr effect enhancement utilizing resonant excitation of SPPs in 1D plasmonic subwavelength nanogratings fabricated entirely from magnetic metal. The use of subwavelength nanostructuring of the nickel film allows the fulfillment of phase-matching conditions for the SPP excitation and enhancement of transversal magneto-optical Kerr
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effect TKE . The idea of the effect is depicted in Fig. 1. The 1D magnetoplasmonic nanograting consists of a magnetic metal film spatially corrugated in one direction with the period of d / 2 with standing for the optical wavelength of the desired spectral range. The phase-matching condition between the electromagnetic wave incident on the subwavelength nanograting and the SPP propagating perpendicular to the metal strips is written as k0 sin + kspp + nG = 0, where k0 and kspp are the wave vectors of incident wave and SPP, respectively; G is the reciprocal vector; n is the diffraction order; and is the angle of incidence. The only way to fulfill the phase-matching in such subwavelength grating is the use of the 1st diffraction order corresponding to n = -1 in the phase-matching condition. A graphical representation of the SPP phase-matching is shown in Fig. 1 a as the intersection of two dispersion laws, kspp and k0 = c G namely, the SPP dispersion law - k0 sin . This point corresponds to Wood's anomaly16 as diffracted incident light propagates along the surface and induces resonantly the SPP wave. The samples studied are nickel films with the thickness of h 100 nm thermally deposited onto a polymeric sub-

Electronic mail: fedyanin@nanolab.phys.msu.ru.

FIG. 1. Color online a Graphical representation of the SPP phasematching as the crossing of dispersion laws of interacting waves. b Schematic of the 1D magnetoplasmonic nanograting and configuration of the phase-matching for the SPP excitation. c The AFM image of the all-nickel magnetoplasmonic nanograting. Black bar is equal to 1 m. d Fourier transform of the AFM image in the reciprocal space visualizing the reciprocal vector G. © 2010 American Institute of Physics

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FIG. 2. Color online a Reflection spectra of 1D magnetoplasmonic nanograting measured for different angles with 2° steps. Dark is for minimal and light is for maximal reflectivity. Inset shows the SPP phase-matching condition with kx = k0 sin . b Particular reflection spectra measured at = 35° and = 68°.

FIG. 3. Color online a Reflection spectra of 1D magnetoplasmonic nanograting measured for different angles with 5° steps, = 60°. Dark is for minimal and light is for maximal reflectivity. Insets show the phaseangles. matching triangles for the SPP excitation for three particular b Representative reflection spectra measured at = 140°, = 165°, and = 180°.

strate having 1D spatial profile with a modulation period of d 320 nm and a depth of a 50 nm. The corrugated nickel film is continuous since its thickness is larger than the modulation depth. The reference nickel film of the same thickness was deposited onto the plain substrate under the same sputtering conditions. Due to small thickness of the skin depth in nickel, being hskin 20 nm, the influence of the nickel backside is neglected. A typical image of the sample surface acquired by an atomic-force microscope AFM is shown in Fig. 1 c and demonstrates high reproducibility of the spatial modulation of the sample. Fourier transform of the AFM image depicted in Fig. 1 d has two bright spots in the reciprocal space corresponding to the reciprocal vector G of the periodic structure. Higher Fourier harmonics are neglected because they have significantly smaller amplitudes. for the Figure 2 shows reflection spectra R , p-polarized light. Sharp and angle-dependent resonance corresponding to Wood's anomaly is observed. The drop in reflectivity indicates additional channel for the light energy redistribution associated with the excitation of the SPP mode as the 1st diffraction order starts propagating along the sample surface. The angular dependence of this feature is defined by the SPP dispersion relation Wood = d + sin with = Ni Ni +1 -1 and Ni being the nickel dependence calculated taking into permittivity. The Wood account the Ni dispersion is shown in Fig. 2 by black dashed curve and correlates well with reflection minima. Meanwhile, the angular dependence of the 1st diffraction order and shown in Fig. 2 position defined as -1 = d 1 + sin by white dotted curve is slightly shifted from the experimental minima in reflection spectra. The absence of resonances for the s-polarized light also proves the SPP origin of the observed features. The SPP excitation is ineffective at small angles making Wood's anomaly superficial. The increase of the normal component of the incident wave at oblique incidence leads to the more efficient coupling of the input electromagnetic field with the normal component of the SPP wave. Due to large light absorption in magnetic metals in the visible, the phase-matching condition for SPP is spread into the interval proportional to the relative value of Ni. The full width at half magnitude FWHM of Wood's anomaly is ap-

proximately 30 nm that significantly exceeds the FWHM value of 10 nm observed in periodic gold gratings.17 The full width of plasmonic resonances in noble-metal gratings is mostly defined by the radiative damping of SPPs which leads to the Fano-type shape of the resonances.17 The radiative damping is the result of the SPP coupling with the far-field continuum and is connected with the SPP propagation length lspp. The radiative damping in the nickel magnetoplasmonic nanogratings is negligible since for Ni = -9.3 + 13.6i at 620 nm the SPP propagation length is lspp 500 nm that is comparable with the period of the structure. The imaginary part of nickel permittivity, Ni, is larger than the real part, Ni, which is opposite to noble metals, and the Wood's anomaly width is mostly defined by absorption damping of SPPs in nickel. Another possibility to tune the central wavelength of the SPP resonance is the change of the azimuthal angle between the plane of incidence and the reciprocal vector under noncollinear SPP excitation. The spectral position of Wood's 2 anomaly is then defined from the equation kspp = G2 2 + k0 sin - 2Gk0 sin cos , with kspp = k0. Figure 3 shows reflection spectra R , measured for the p-polarized light. The strongest Wood's anomaly is observed for = 0° and = 180° at 610 nm. In this case, kspp is oriented collinearly with G, and polarizations of input light and SPP are uniplanar. As SPP propagates out of the incident plane, Wood's anomaly becomes blueshifted, and the efficiency of the incoming field coupling into the SPP is rapidly decreased. The transversal magneto-optical Kerr effect in 1D magnetoplasmonic nanogratings is measured at = 0° for the p-polarized light using the lock-in technique with application of ac-magnetic field with the maximal strength of 1.5 kOe, which is far above the saturating level. Figure 4 shows spectral dependences of the TKE value = I - I0 / I0, where I and I0 are reflected light intensities with and without external magnetic field, respectively, measured in the magnetoplasmonic nanograting and in the reference sample of the plain nickel film. Both spectra show the same trend of the TKE value decrease with the wavelength increase associated with the spectral dependence of the nickel gyration constant. Additionally, TKE in the magnetoplasmonic nanograting shows

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subwavelength all-nickel nanogratings due to resonant excitation of surface plasmon-polaritons. The angular-spectral tunability of the SPP excitation allows the control of magneto-optical response in magnetoplasmonic nanogratings in the desired spectral region, which can be applied in magnetophotonic devices. The work was supported by Russian Foundation of Basic Research and Ministry of Education and Science under Grant Nos. 10-02-91170, 10-02-92115, P946, and P918.
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FIG. 4. Color online TKE spectra of 1D magnetoplasmonic nanograting circles and the reference plain nickel film dashed curve . The solid curve shows the reflection spectrum measured at = 68° and = 0° with Wood's anomaly at 625 nm.

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the resonant enhancement at Wood's anomaly. The TKE value at 625 nm is approximately one order of magnitude larger in comparison with the plain nickel film. The TKE spectrum in the vicinity of the SPP resonance has an asymmetrical shape and even changes the sign. The TKE enhancement can be phenomenologically interpreted as a result of the SPP dispersion curve shift upon the magnetization reversal in magnetic media. Then, the Wood's anomaly minimum is also shifted because of the change of the SPP phase-matching condition. Since the TKE effect is proportional to the difference between reflection coefficients for opposite magnetization directions normalized at the mean reflection coefficient, the TKE spectrum has an asymmetric resonant form in the spectral region of the SPP excitation, which agrees with experimental data. Note that pure nickel subwavelength grating without any noble-metal films supports the excitation of surface plasmons strong enough to achieve the TKE enhancement comparable with the case of trilayer Au/Co/Au films.15,18 In conclusion, transversal magneto-optical Kerr effect is shown to be almost one order of magnitude enhanced in

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