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Second International Conference of CIS IHSS on Humic Innovative Technologies

«Natural and engineered nanoparticles in clean water and soil technologies»


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October 29 ­ November 2, 2012, Lomonosov Moscow State University, Moscow, Russia 29 ­ 2 2012 ., .. , , http://www.humus.ru/hit-2012/eng/



"HIT-2012" « » PROGRAM OF THE CONFERENCE "HIT-2012" "NATURAL AND ENGINEERED NANOPARTICLES IN CLEAN WATER AND SOIL TECHNOLOGIES" 29 , 2012, / October 29, 2012, Monday Arrival Day 21:30 ­ 24:00 " " Bus Excursion "Moscow at night" 30 , 2012, / October 30, 2012, Tuesday 09:00 ­ 10:00 Registration of the conference participants 2 - . (-), , 1- , Lobby of the B2 lecture hall ­ the Losev international center, the Shuvalovsky building on the new territory of the MSU, the first floor, sector B 10:00 ­ 10:30 OPENING OF THE CONFERENCE 2 ­-, , 1- , Lecture hall B2 ­ the Losev Center, Shuvalov building, the 1st floor, sector B Welcome Addresses , , Valeriy Lunin, academician of RAS, Dean of the Department of Chemistry, Lomonosov MSU , , Gleb Dobrovolsky, academician of RAS, Director of the Institute of Ecological Soil Science of the Lomonosov MSU , - , Sergey Ponomarenko, correspondent member of RAS, Enikolopov Institute of Synthetic Polymeric Materials of RAS

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, , . .. , - Serafim Chukov, Professor, Dokuchaev Soil Science Society, Saint Petersburg state University , « » HIT-2012 Rodion Poloskin, "Actualization of ecological technologies" Ltd. - General sponsor of the HIT2012 conference , Irina Perminova, Welcome from the Organizing Committee ­ KEYNOTE LECTURES : -. .. . .. Chairs of the session: Corr. member of RAS S.A. Ponomarenko and Prof. S.Yu. Bratskaya 10:30-11:00 Steve Leharne (Greenwich University, United Kingdom) Nanoparticle stabilised emulsions: Do they offer remedial opportunities? ( , ) , : 11:00 ­ 11:30 Etelka Tombacz (University of Szeged, Hungary) Natural macroligands and magnetic nanoparticles: spontaneous processes and rational design ( , ) : 11:30 ­ 12:00 - Coffee break RATIONAL DESIGN OF NANOPARTICLES AND THEIR USE IN ENVIRONMENTAL TECHNOLOGIES 2 ­-, Lecture hall B2 ­ the Losev Center, Shuvalov building : . .. . .. Chairs of the session: Prof. S.N. Kalmykov and Dr. M. Yu. Vozhdaeva 12:00 ­ 12:30 ( ­ Invited lecture) ( , ) Leonid Kustov (Institute of Organic Chemistry of RAS, Moscow) Rational design of engineered nanomaterials for water and soil remediation

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12:30-13:00 ( ­ Invited lecture) ( , ) « » Eugene Goodilin (Department of Materials Science, Lomonosov MSU) Soft chemistry in preparation of therapeutic and diagnostic nanoparticles 13:00-13:15 ( , ) , Alexander Ivanov (Institute of petroleum chemistry of SB RAS, Tomsk) Sorption capacity of peat mechanoactivated in the presence of iron oxyhydroxide 13:15 ­ 13:30 ( ) Anna Romanchuk (Department of Chemistry, Lomonosov MSU) Graphene Oxide for Effective Radionuclide Removal 13:30 ­ 13:45 . ­ , - , , Fe3O4@TiO2 «-» Mourad Harir et al. Helmholtz Center Munich, German Research Center for Environmental Health, Neuherberg, Germany Photocatalytic efficiency of Fe3O4@TiO2 Core-Shell magnetic microspheres in degrading micropullutants in water interface 13:45 ­ 14:45 - Lunch - SOIL AS NANOSTRUCTURED ORGANO-MINERAL SYSTEM 2 ­-, Lecture hall B2 ­ the Losev Center, Shuvalov building : . .. . .. Session Chairs: Prof. S.N. Chukov and Prof. V.A. Terekhova 14:45 ­ 15:15 ( ­ Invited lecture) ( ) Gennady Fedotov (Institute of ecological pedology Lomonosov MSU) Nanostructured organization of soils

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15:15 ­ 15:45 ( ­ Invited lecture) ( ) Alexander Shinkarev (Kazan State University) Clay-organic interactions in soils as one of previous stages at formation of clay deposits 15:45 ­ 16:00 ( , , , ) - Elena Lapteva (Institute of Biology, Komi Science Centre, Ural Branch, RAS, Syktyvkar) Influence of Clear-Cut on Humic Substances of Podzolic Soils in the Spruce Forests of European North-East 16:00 ­ 16:15 ( , ­ . ) : Olga Alexandrova (Osnabrueck University, Germany ­ Ural Federal State University, Ekaterinburg) Investigation of Organic Xenobiotic Chemicals in Soils: A Method of Paramagnetic Probes to Assess Mechanisms of Binding 17:00 ­ 21:00 - ­ Get together

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31 2012, () ­ October 31, 2012, Wednesday (Halloween) NATURAL AND SYNTHETIC NANOOBJECTS IN WATER ENVIRONMENTS 2 ­-, Lecture hall B2 ­ the Losev Center, Shuvalov building : ... .. . Session Chairs: Dr. habil. K.A. Kydralieva and Dr. Harir 9:00 ­ 9: Markus Stability 30 ( ­ Invited lecture) ( , ) Delay (Karlsruhe Institute of Technologies, Germany): and interactions of engineered nanoparticles in aquatic systems.

9:30 -10:00 ( ­ Invited lecture) ( , . .. , ) Vera Terekhova (Soil Sciences Department of the Lomonosov MSU, Severtsov Institute of Ecology and Evolution Problems of RAS, Moscow) Toxicity assessment of engineered nanoparticles in soil and water. 10:00 ­ 10:15 ( , ) Nadezhda Belokonova (Ural State Medical Academy, Ekaterinburg) Evaluation of organic contaminants properties in drinking water 10:15 ­ 10:35 ( «», , ­ HIT-2012) . Ekaterina Wagner (Water utility "Ufavodokanal", Ufa ­ Sponsor of the HIT-2012) Influence of natural water dissolved organic matter on the quality of drinking water of Ufa 10:35 ­ 11:00 ­ Coffee break : WATER QUALITY: ROLE OF ORGNAIC MATTER 2 ­-, Lecture hall B2 ­ the Losev Center, the Shuvalovsky building : ... .. ... .. Session Chairs: Dr. habil. L.V. Gandurina and Dr. N.Yu. Grechischeva 11:00 ­ 11:30 ( ­ Invited lecture) ( «», ) ­ Nadezhda Kutseva (Analytical Center ZAO "ROSSA", Moscow) Chemical analysis of water - quality assessment of water treatment 7


11:30 ­ 11:45 ( «», - HIT-2012) Margarita Vozhdaeva (Water utility "Ufavodokanal", Ufa, - sponsor of HIT-2012) Total technogenic organic carbon in water 11:45-12:00 ( , , , ) - Elena Shamrikova (Institute of Biology, Komi Science Centre, Ural Branch, RAS, Syktyvkar) Determination of low molecular weight organic acids in water extract from soils by GLC-MS 12:00 ­ 12:15 ( , ) Nikolay Lavrik (Institute of chemical kinetics and combustion of the Siberian Branch of RAS, Novosibirsk) The Study of Complexation Features of Humic Acids Macromolecules with Metal Ions by The Spectral Dependence of the Fluorescence Quenching Efficiency 12:15 ­ 12:30 ( ) : Eugene Shirshin (Department of Physics, Lomonosov MSU) Molecular Weight of Humic Substances: Correlation with Fluorescence Quenching of Pyrene 12:30 ­ 12:45 ( . .. ­ . , , ) , XAD-8, - PPL C18. Ivan Dubinenkov (Emanuel Institute of Biochemical physics of RAS, Moscow, - Alfred Wegener Institute for Polar and Marine Research, Bremerhaven, Germany) Comparative study on molecular profiles of the DOM isolated from the Kolyma River in the Russian Arctic using XAD-8 resin, DEAE-Cellulose, PPL-, and C18 ­ Cartridges 13:00 ­ 13:30 OPEN MEETING OF THE MEMBERS OF THE CIS IHSS CHAPTER . . 446 (4- ) Department of Chemistry of the Lomonosov MSU, auditorium 446 (the 4th floor)

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13:30 ­ 17:30 LUNCH AND POSTER SESSION IN THE HALLOWEEN MOOD , 2- , () Department of Chemistry, the 2nd floor, lobby of the Big Chemistry Auditorium : ..-.. .. , . , ... , . , ..-.. Chairs: Dr. Alexandrova, Dr. Delay, Dr. Kulikova, Dr. Leharne, and Dr. Shirshin 18:00 : « » Departure for the cultural program by choice: Circus on the Lenin Hills or Bus Excursion "Ghosts of Moscow"

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1 2012, ­ November 1, 2012, Thursday NATURAL MACROLIGANDS AND PROSPECTS OF THEIR APPLICATIONS 2 ­-, Lecture hall B2 ­ the Losev Center, Shuvalov building : . . .. Session Chairs: Prof. Tombacz and Prof. N.A. Belokonova 9:00 ­ 9:30 ( ­ Invited lecture) ( , ) Svetlana Bratskaya (Institute of Chemistry, Far-East Branch if the Russian Academy of Sciences, Vladivostok): Chitosan and its derivatives in drinking and waste waters treatment. 9:30 ­ 10:00 ( ­ Invited lecture) ( , ) - Miloslav Pekar (Technical University of Brno, Czech Republic) Humic-chitosan gels as biocompatible nanocontainers. 10:00 ­ 10:15 ( , , ) - Larisa Parfenova (Institute of ecological problems of the North, Ural Branch of RAS, Arkhangelsk) Lignin and Humic Polymers as Natural Surfactants. 10:15 ­ 10:30 1 3 ) Ivan Kovalev (Department of Lignin as a precursor of humic ( , ) ( Soil Science of the Lomonosov MSU, Moscow) substances in soils (according to 13C NMR spectroscopy)

10:30 ­ 11:00 - Coffee break COMMERCIAL HUMIC PRODUCTS AND THEIR APPLICATIONS IN AGRICULTURAL TECHNOLOGIES : . . ..-.. .. Session Chairs: Prof. M. Pekar and Dr. habil. O.A. Shapoval 11:00 ­ 11:15 ( , ) : Olga Yakimenko (Department of Soil Science, Lomonosov MSU, Moscow) Commercial Humic Products: the Role of Organic Matter Genesis for Application in Environmental Technologies 10


11:15 ­ 11:30 ( « « » , . - HiT-2012) «» Oleg Gladkov (AET Ltd, Saint Petersburg, Russia. ­ General Sponsor of the HIT-2012) Assessment of chemical composition and comparative biological efficiency of solid and liquid grades of humic product "Lignohumate" 11:30 ­ 11:45 ( ­ , , ) 12/21: () Wolfgang Nowick (daRostim Private Institute for Applied Biotechnology, Glauchau, Germany) Tandem12/21: International long-term program to increase the biological soil fertility and to establish sustainable biological nutrient resource in the soil by applying PhytoHuminCompounds (PHCs) 11:45 ­ 12:00 ( - , -) Andrey Komarov (Agrophysical Research Institute, Saint-Petersburg) Perspectives of Use of Humic Preparates as Mechanism to Control the Plants Productivity 12:00 ­ 12:15 ( , .. ) Natalia Kulikova (Department of Soil Science, Lomonosov MSU, Bach Institute of Biochemistry of RAS, Moscow) Unexpected Role of Humic Acids in Wax Biosynthesis of Higher Plants 12:15-13:30 Panel discussion 13:30 ­ 15:00 ­ Lunch

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YOUNG SCIENTISTS SESSION : . .. ... .. Session Chairs: Prof. I.V. Sokolova and Dr. V.A. Kholodov 15:00 ­ 15:15 ( , ) Vladimir Tikhonov (Soil Science Faculty, Lomonosov MSU, Moscow) Sorption of humic substances by bacteria and related biological effects 15:15 ­ 15:30 ( , , ) Olga Lisovitskaya (Department of Soil Science, Lomonosov MSU, Moscow Effect of K-humate on Diamond Nanoparticles Phytoactivity 15:30 ­ 15:45 ( , ) Kyrill Laptinskiy (Department of Physics, Lomonosov MSU, Moscow) Determination of nanodiamonds adsorption activity to heavy metals in waters by methods of laser IR and Raman spectroscopy 15:45 ­ 16:00 . ( , ) Cyrill Yerokhin et al. (Belgorod State National Research University, Belgorod) Self-organized Nanoparticles in Ruff and Fenton Systems 16:00 ­ 16:15 . ( , ) Alexander Volikov et al. (Department of Chemistry, Lomonosov MSU, Moscow) Self-Assembly of Silanol Derivatives of Humic Substances into Nanocoatings and Its Remedial Applications 16:15 ­ 16:30 .( , ) . Elizaveta Maltseva et al. (Institute of Petroleum Chemistry SB RAS, Tomsk) Adsorption properties of humic acids of mechanoactivated oxidized brown coal of Mongolia

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16:30 ­ 16:45 ( , ) , : Tatiana Sorkina (Department of Chemistry, Lomonosov MSU, Moscow) Mechanism of Humic-Stabilized Feroxyhyte Nanoparticles Formation: Mossbauer Study of Frozen Multicomponent Reaction Mixture 16:45 ­ 17:00 - Coffee break 17:00 ­ 17:30 - Press - conference 17:30 ­ 18:45 , , General Discussion, Concluding remarks, official closing of the conference 19:00 ­ 22:00 - Conference Dinner (2- ) Canteen of the Department of Chemistry of the Lomonosov MSU (the second floor)

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2 2012, - November 2, 2012, Friday , . 446 Department of Chemistry, auditorium 446 10:00 ­ 12:00 : " " ROUND TABLE DISCUSSION: "PROSPECTS OF APPLICATION OF HUMIC SUBSTANCES AND NANOPARTICLES IN CLEAN UP TECHNOLOGIES" : ... .. . . Moderators: Dr. habil. S. Bratskaya and Prof. S. Leharne 12:00 ­ 14:00 Excursion to the Museum of the Earth Science of the Lomonosov MSU. 14:00 ­ 15:30 - Lunch DEPARTURE OF THE CONFERENCE PARTICIPANTS

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POSTERS 31 , 2012, () ­ October 31, 2012, Wednesday (Halloween) 13:30 ­ 17:30 Halloween ( , 2- , ()) Posters in the Halloween mood (Department of Chemistry of the Lomonosov MSU, the second floor, lobby of the Big Chemistry Auditorium) P-1 Dmitry Abroskin . Visualization of Humic Acids Penetration in Higher Plants Vascular System Using Tritium Autoradiography . P-2 Natalia Bakanova et al. (Peoples' Friendship University of Russia, Moscow) Lignohumate ­ new results of NMR and MS . ( , ) ­ - P-3 Yulia Buchatskaya et al. (Lomonosov MSU, Chemistry Department, Moscow) Sorption preconcentration of radionuclides using detonation nanodiamonds . ( , ) . P-4 Maria Chernysheva et al. (Department of Chemistry of the Lomonosov MSU, Moscow) Radiochemical approach in modification of carbon based nanomaterials with biopolymers . ( , ) P-5 Dmitriy Gabov et al. (Institute of Biology, Syktyvkar) Comparison of different methods of extraction and cleanup of polycyclic aromatic hydrocarbons from soils . ( , . ). P-6 Oleg Gladkov et al. (A.E.T., Ltd (NPO RET)) Efficiency of Combined Application of Lignohumate with Microbiological Product BAC on Cleaning Rate of Soil after Oil Pollution . ( «», -) BAC 15


P-7 Marina Gladkova et al. (Soil Science Faculty, Lomonosov MSU, Moscow) Effect of potassium humate on nanodioxide titanium toxicity . ( ) P-8 Natalia Grechishcheva et al. (Gubkin Russian State University of Oil and Gas, Moscow) Stabilization of oil-in-water emulsions using organoclays consisting of kaolin modified with humic substances: remedial prospects. . ( .. , ) , : P-9 Abdulgalim Isaev et al (Dagestan State University, Makhachkala) Photocatalytic Oxidation of Organic Dye With Use the Electrochemical Synthesis of Cu2O and Fe2O3 nanoparticles . ( , ) Cu2O Fe2O3 P-10 Vyacheslav Kan et al. (Institute of Soil Science and Agricultural Chemistry after U.U. Uspanov of the Republic of Kazakhstan) Biotechnological model of soil fertility of Kazakhstan . ( . .. ) P-11 Vladimir Kholodov et al. (Dokuchaev Soil Science Institute, Moscow, Lomonosov MSU, Moscow) Contact Angles of Humic Substances Complexes with 1:1 and 1:2 Clay Minerals . ( .. , ) 1:1 1:2 P-12 Olga Klein et al. (A.N. Bach Institute of Biochemistry of RAS, Moscow) Interaction of Coal Humic Substances with White Rot Fungi: an Approach with Tritium Labeled Preparations . ( .. , ) : P-13 Alexey Kononikhin et al. (Institute of Energy Problems of Physics of RAS, Moscow) Comparative studies of the Kolyma River and permafrost DOM using FTICR MS . ( , ) 16


P-14 Andrey Konstantinov et al. (Lomonosov MSU, Department of Chemistry, Moscow) Compositional Study of Mumiyo Samples Originated from Different Mountainous Regions Using Solution-State NMR Spectroscopy and High-Resolution Mass Spectrometry . ( , ) P-15 Andrey Konstantinov et al. (Department of Chemistry, Lomonosov MSU) Complex analysis of the quality of dissolved organic matter on the example of the samples isolated from the Ural Lakes . ( , ) , P-16 Irina Kuznetsova, et al. (Institute of Environmental Problems of the North of the Ural Branch of RAS, Arkhangelsk) Binding of heavy metals by humic acids: pH and ionic strengths effects . ( , ) : P-17 Galina Larina et Characteristics of al. (Gorno-Altaisk State University, Gorno-Altaisk) Humic Acids of Peat in Gorny Altai . (- , -)

P-18 Kamila Kydralieva et al. (Institute of Chemistry and Chemical Technology, Bishkek, Kyrgyzstan) Humus Status in Technogenic Soils of Kyrgyzstan . ( , , ) P-19 Denis Pankratov et al. (Department of Chemistry, Lomonosov MSU, Moscow) The interaction of the metal iron with humic substances . ( , ) P-20 Miloslav Pekar et al. (Brno University of Technology, Brno, Czech Republic) Simple technique for modeling transcuticular transport of liquid humates in leaves . ( , , )

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P-21 Olga Philippova et al. Department of Soil Science, Lomonosov MSU Influence of Peat Humic Substances and Their Si-Derivatives on Soil Structure . ( , ) Si- P-22 Maria Pukalchik et al. (Department of Soil Science, Lomonosov MSU, Moscow) Modeling remediation of urban chemical polluted soil using two types of humic-based sorbents . ( , ) P-23 Natalia Shorina et al. (Institute of ecological problems of the North, Ural Branch of RAS, Arkhangelsk) The study of dissolved organic matter of Northern Dvina river in the different hydrological seasons by IR spectroscopy and elemental analysis . ( , , ) - . P-24 Irina Sokolova et al. (Tomsk State University, Tomsk) Photochemical Properties of Humic Substances in Water Solutions . ( , ) P-25 Anna Yurishcheva et al. (Moscow Aviation Institute, Moscow) Effect of Humic Substances Concentration on Properties of Magnetic Nanoparticles . ( , ) P-26 Anna Zavarzina et al. Synthesis of Humic-Clay Nanoparticles By Laccase-Catalyzed Heterophase Polymerization of Soluble Precursors . - , P-27 Alexander Zherebker et al. (Department of Chemistry, Lomonosov MSU, Moscow) Synthesis of model humic substances and their analysis using Fourier Transform Ion Cyclotron Resonance Mass Spectrometry . ( , ) - P-28 Yury Zhernov et al. (Samara State Medical University, Samara) Biological activity of different fractions of natural humic substances from peloids . ( , ) 18