Äîêóìåíò âçÿò èç êýøà ïîèñêîâîé ìàøèíû. Àäðåñ îðèãèíàëüíîãî äîêóìåíòà : http://magn115.phys.msu.ru/diploma/2016/Doronin2015.pdf
Äàòà èçìåíåíèÿ: Sat Dec 19 12:08:30 2015
Äàòà èíäåêñèðîâàíèÿ: Sun Apr 10 01:38:20 2016
Êîäèðîâêà:
..


Investigation of the structural, magnetic and magneto-optical properties of the thin-film systems based on cobalt and bismuth

, -

6 : ., ., « » 2015 . . . .C.

­ 2015


1. __________________________________________ 5 1.1. _________________________________________________ 5 1.2. _ 1.2.1. - _ 1.2.2. ______ 1.2.3. - ___ 1.2.4. ___ 1.2.5. _________ __ __ __ __ __ __ _____ _____ _____ _____ _____ _____ __ __ __ __ __ __ _____ _____ _____ _____ _____ _____ __ __ __ __ __ __ _____ _____ _____ _____ _____ _____ __ __ __ __ __ __ ___ ___ ___ ___ ___ ___

_________________________________________________ 3



2. ________________ 22

1.3. __ 1.3.1. ________________________________ 1.3.2. ______________________________________________________ 1.3.3. ______________________________________________ 1.3.4. ______________ 1.3.5. 5d ______________________________ 1.3.6. Fe ______________________________ 1.3.7. Bi _________________ 1.3.8. ______________________

_9 _9 _9 10 10 11

12 12 13

14 15 16 18 18 19

2.1. _____________________ 22 2.2. _______________________________________________ 23 2.3. __ 27 2.4. ______________________________ 28 2.5. _____________________ 29

3. ___________________ 31

3.1. ____________________ 31 3.2. _ 31 3.3. - ________________________________________________________ 38

_______________________________________________ 43
2




XX . - , 2007 . , GMR, 1988 (GMR),



, (MR), , .

(MRAM), , , - , .

, , - ,

. GMR TMR ,

[1] , .

[2]. ,

(Fe, Co) // (Ag, Au), (Ta, Mo, Pt, Pd)

. ( - Fe, Co) (): (Si). , ,
3


( ).



, , . , , , , (Bi) .



, ,



. - .



, Co/Bi/Co Bi/Co .



4


1.
1.1.

. 70- , , , - .

[3], . . . ,

[4],

, . , - . , - ( ). - , ,

,

. . , Si ­ i- . , S ­ , : H = - JijSiSj, Jij ­ [5]. , , [8, 9]

( ) [6, 7], , Fe, Co Ni. ,

, .

5


, . - ( , ( ). , - , ,

), ( 0.1 eV/atom) , (~ 0.1 meV/atom) (~10 eV/atom), , , . [10 - 12]: . = (m)2,



­ , m = M/MS ­ , MS . , ,

. , - [13 ­ 16]. : e = Ku(1-32) + Ku'(1-32)2 + ..., e
uni

uni

= K1i>ji2j2 + K2122232 + ...,

i ­ , Ku, K1 K2 ­ . , ( ), - . 0.1 ­ 1 -2. ,

6


:

,

Hd ­ , , , , , ). , U. U - S = nM = - M, ( n -

ems = 2HdM,

, ,

lex = (A/2MS2) l

1/2

, . l KS , w. [17].
dw

, [4] , lS = (Aw/KS)1/2,

dw

= (A/K)1/2.

L ~ (A/K)1/2.

,

, , D . , , [16], : , , D >> L



. () ,

7


(K1)

1 /2

/ MS D

1 ­ . D < < L


.



. . , , , : , , , N

N , V = L3.





14D6 / 3.

:

:

HC K/MS, HC K


/MS = 14D6 / MS3.

, , :

, ,

L = (A/K)1/2,
- , - .

8


1.2.
. 1970 ,

. ,

1.2.1. -

.

- 1960-

,

,

( 10-8 ).

10-6 %. , .

1.2.2.
. (). . , ()

, . , , ,

. .
9


, ,

. , , , , . , , . 1.2.3. - , - ,

,

, .

( . 1.2.4. . , (). ­

) .

.

. ,

, . ,

.

.
10


, , . ,

. , , , . , , .

, ,

1.2.5. . . .



,

, , .



11


1.3.
. , . , ,

, , , , . . , ,

,

. ,

, , , , , . . , , ,

1.3.1.
, . ,

, , . 3.2 . Fe 2.2 , Fe u (111) 2.7 , Ag(111) , . Fe u (001) 4.0 .
12




, Co .

Fe, , , , Cu (001) W(001),

Co . , [18]. ,

«» . [19]

. Co NiFe 5-20 r, Ta Cu Co, NiFe .

r, Ta Cu , 20 .

1.3.2.
[20]

Ni/Ge Ge/Ni/Ge/Ni/Ge. 150 10 . Ni 12.5 , 14 , 17.5

. Ni , Ni, . «» Ni ( ~ 5),

Ge . . Ge Ni: ,

,

, Ni . Ni .

Ge Ni,

13


. .

Ni 40%,

.

,

. Ge Ni . , , .

Ge Ni. Ni Ge,

1.3.3.















. , (111), 1.8 , - 180 . . 70 . Fe 0.5 (112), .

[21]

(110), . , 50 -

, , . .1 .

14


. 1 .

.

[22]

Si Fe.

.

, ,

, .

1.3.4. .
FeNi () , , NiSO [23]

. . ( ), FeSO4 ( ) 6H8O7 ( ).
15
4


Fe ,

. , . , , , , , , . , , .. . ,

, , . 1.3.5. 5d
CoFeB/MgO (PMA)

. Ta, - PMA . Ta. , Hf . [24] Mo, 5d ­ .



30%, ( 300-450° ) PMA 20%, , , (VSM).

.

16


.2 Ta Mo

Ta, 425 . , Mo . . , , Mo/CoFeB/MgO . Mo . , Mo . , , , Ta

, . 2, , Mo

17


1.3.6. Fe
. , , CoFe CoFe ,

2 . .

, . [25] CoFe , .

NiZn-. , 7 4.5 . , , . . , CoFe NiZn-

1.3.7. Bi
Bi, : Bi 3d­, . [26] , NiFe/Bi/NiFe Bi. 3 15 . Bi , , , , . Bi, 13 , ,
18


,

NiFe 10 , ,

3 . , 3 12


Bi . [27]. 18-20 .

Bi

CoFe/Bi/Co

1.3.8.
C42H [28] ,
28

, . , Ni. 15 0.11 /, 100-200 nm. Ni . 3 , «» .

(), Ni.

,



, ,



. 3 .

, ,

A B ( «» ).

A. , B. ( , ) , B

, ( 700 )

19


«». 2 , B . , , , . . , , , . , . . , ,

, ,

. , , , .

,

. (OLED). , , Alq3 (Alq3 - Al(C9H6NO)3), [29]. Alq3 , . , Alq3 . : 35 Co 150 Alq3, Co,

,

35 Co 300 Alq3 100 Co 150 Alq3. , 100 Co , (AFM) Alq3/Co Alq3. , , Alq3, , 10 . .

20


. , ( 15o) (400 ) , 90 - 295 .

. . 15o. , Alq3/Co 90o . . 4 . . 15o , Co 35 /Alq3 150

. 4. Co 35 / Alq3 150 .

. 5. Co/Alq3 Co/Si .

. 5 , Co/Si Alq3/Co . , Alq3 Co.

, Co

21


2.
2.1. . . 1. , .

, - . . , .

,

2. , .



.



, . . , .



). , ). () . , ). . ( ,

(

.

P- S- (

22


, = MS, MS ­ . .



.

()/S ()/S, S - M

2.2.













, -11. - . 6. ) : ( -12, 1 , . 45.



, . . ,

, ­ tpen. t t
pen p en

[30], 0.5 ­ 6 .

=/4 ( - ).

10 ­ 30

23




2

1
IS

IN

. 6 - , 1 - -102 2 - -50 -11. ­

3 - 2-11 4 - 2-8 5 - -1 6 -

­ - 1 ­

­ 2 - ­

7 - - -24 8 -

,
24

2


( ). , , .

. , , , , ,

2 ­ 3 , 10-4 ­ 10-5. .



-102.

f = 80 . . . :

; U
~

U- - , I0, - f, I

, (­ ) .



2-11, U

U-
~

-1.

- - 2-8

, ,

25


-102, . -1 2-11 . ,

, - () -24. -24 , .

, . . , <>

( ),



, .



, , - ( ~0.5. ~10-4), ,



± 5 .

:

510-5; 20 .



. .



= (I ­ I0)/I0, I I0 ­ , . .
26


, ( D1), - D1 ( D2).

2.3.
, -4. - . 7.

. 7 - -4

, . . , 3, p- - 5, 6. . , 4, 7,

1 2.

8. 8 PbS,
27




. . 11 , 11, . 13. 14 6. . 10.

, , , . 0,5 4 3 .

, , , ,

. , , . 2.4. . ­

, (, ± 2%.



..). . , : , 1. ,

f = 50 .
28


, (f = 80 ).

,

, . . . . S- , S-. , 900 - S- S 1% P. .

- , . ,

­ 10-4, . 10%. 0,1 . 5 %. . , 3. .

2. .

2.5.
Bi . 4·10-7 , 3.8·10 , 250 , , 0.2 50 , Bi/Co 0.5 8 . .
29
-3

Co/Bi/Co Bi/Co

.

Hsub, . Co , tCo, 5 . Bi , tBi, Co/Bi/Co


, CuK . (). Co/Bi/Co Bi/Co -















( ) H. H H H
SUB

(). ( D2).
SUB

( D1), ­

- , > Hs, Hs ­ . .



-4 ( ) 0.5 4.5

30


3.
3.1.

, , . , XRD . - (). Bi . , Bi Bi/Co . Bi .

, Co/Bi/Co Bi/Co

«Nova», . , , Ra, 0.4 - 0.5 . Ra

3.2. Co/Bi/Co Bi/Co

. . . 8- 11 , Co/Bi/Co Bi/Co .

31


.8 , Co/Bi/Co .

.9 , Bi/Co

.10 , Co/Bi/Co .
32


. 11 , Bi/Co .

, D1 D2 , . . (), , () = 250 , . , , , . . [31], . . ,

,

NiFe Fe,

1.2 7%. ,

.
33


1937 .

. [32]. . , , D2 ,

. . , t , t
Bi

. , , D1 , , tBi.
Bi

, Co/Bi/Co -

(. 10). Bi/Co Bi (. . 11 12).

. , , , HS,

Co/Bi/Co , D1 .

. 12 Bi ,

34


Bi/Co , D1 .

. 13 Bi ,

, Hc, , Hs, . HC(tBi) HS(tBi) Bi/Co ,

, 12 13, ,

, . , Bi , t B i. [33],

, Bi

. [34] ,

. , t Bi HC HS Bi/Co .
Bi



Bi . . [33, 35, 36] , [37],
35

HC(tBi) HS(tBi) /Bi/Co




. , HC(tBi) Hs(tBi) Co/Bi/Co Bi ( () () ). tBi ( 0.2 50 ) HC HS Co/Bi/Co , , [33, 35, 36]. HC, 2, 1 15 tBi 0.5 50 . H = 0 .

.



Hs ,

,

. , HS(tBi) , JAF J /Bi/Co J
AF AF

, JAF, tBi. MS t ­ . - . 1.3·10-2 /2. , - HSMSt/4,

0 180, - Co/Bi/Co

. , J Bi .
36

.


.















- [38, 39], /F , F ­ . /
F

, , ( Quantum Well States, QWS's) . , 1- 1.2 .

0.3 ­ 0.4 .

[40, 41], . . , .

QWS's



, Co/Bi/Co H(tBi)

HS(tBi) t
Bi

. , .



37


3.3. - - Co/B/Co Bi/Co ,

.

0.5 4.0 , 13 14.



. 14 , Co/Bi/Co .

38


. 15 , Co/Bi .

.

, . 14 15, - .

- Co/Bi/Co , 0.4- 3.6 , , 5 . 1.5 , - Co/Bi/Co Co tBi = 10 . tBi > 3.6 0.5 , .

- Co/Bi/Co Bi/Co

, , tM, t (tinf). , t Co/Bi/Co t
Bi M inf

. [30] Fe Co 20-

24 0.5 ­ 4.0 . , = 0.4-3.6 , tinf.

39


10 . , tCo= 5 . t
Bi

( ) .

> 10

, - .

(Co) (Bi) . , Bi/Co . , -

- , tBi = 0.5 .

40


. 1. , , . 2. /Bi/Co Bi/Co

. . 3.

, D2 ,

, Co/Bi/Co
Bi

, D1 , , tBi: t t 4.
Bi

.

- . Bi/Co

,

/Bi/Co Bi/Co . 5.

(tBi) s(tBi)

Bi . 6. ). (

(tBi) s(tBi), /Bi/Co ,

, ( 0.4 50 ) .
7.

(tBi) s(tBi) /Bi/Co

Fe, Co/Ta, Mo, Zr, Pt, Pd/Fe, Co

.

41


8.

, 1.5 , 5 . 9. t
Bi

Co/Bi/Co t

Bi

= 0.4 - 3.6 ,

Co/Bi/Co Bi/Co

, - .

> 3.6 0.5 , .

(Co) (Bi) . ,

42


.
1. Parkin S.P., More N., Roche K.P. "Oscillations in exchange coupling and magnetoresistance in metallic superlattice structures: Co/Ru, Co/Cr, and Fe/Cr". Phys. Rev. Lett. 64 (1990) 2304-2307. 2. Su W.B., Chang C.S., Tsong Tien T. "Quantum size effects on ultra-thin metallic films". Taiwan, Roc (2009) 1-87. 3. Arthur J.R., "Molecular Beam Epitaxy" Surf. Sci. 500 (2002) 189-217. 4. Vaz C.A.F., Bland J.A.C., Lauhoff G. "Magnetism in ultrathin film structures". Rep. Prog. Phys. 71 (2008) 1-78. 5. Hurd C.M. "Varieties of magnetic order in solids". Contemp. Phys. 23 (1982) 469493. 6. Stoner E.C. "Collective Electron Specific Heat and Spin Paramagnetism in Metals". Proc. R. Soc. Lond. A 154 (1936) 656-678. 7. Stoner E.C. "Collective electron ferromagnetism". Proc. R. Soc. Lond. A 165 (1938) 372-414. 8. StÆhr J. and Siegmann H.C. "Magnetism: From Fundamentals to Nanoscale Dynamics" Berlin: Springer (2006). 820. 9. Donath M. "Band-Ferromagnetism". ed K. Baberschke et al Berlin: Springer (2001) 267. 10. Landau L.D. and Lifshitz E.M. "On the theory of the dispersion of magnetic permeability in ferromagnetic bodies". Phys. Z. Sowjetunion 8 (1935) 153-169. 11. Carr W.J.Jr., "Encyclopedia of Physics vol XVIII/2" ed S. FlÝgge Berlin: Springer (1966). 274. 12. Kittel C. "Quantum Theory of Solids". 2nd edn New York: Wiley (1987). 425. 13. Kanamori J. "Magnetism vol I.". ed S Rado New York: Academic (1963). 127. 14. Farle M. "Ferromagnetic Resonance of Ultrathin Metallic Layers". Rep. Prog. Phys. 61 (1998) 755-826. 15. Van der Laan G. "Microscopic origin of magnetocrystalline anisotropy in transition metal thin films". J. Phys.: Condens. Matter. 10 (1998) 3239-3253. 16. StÆhr J., "Exploring the microscopic origin of magnetic anisotropies with X-ray magnetic circular dichroism (XMCD) spectroscopy." J. Magn. Magn. Mater. 200 (1999) 470-497. 17. Herzer G., "Grain size of coercivity and permeability in nanocrystalline ferromagnets" IEEE Transaction on Magnetics 26 (1990) 1397-1402. 18. G. Bihlmayer, P. Ferriani, S. Baud, M. Lezaic, S. Heinze, S. Blugel. "Ultra-Thin Magnetic Films and Magnetic Nanostructures on Surfaces". 32 (2006) 151-155

43


19. Xiaofang Bi, Liqing Can, Xiaoyan Ma, Shengkai Vong, Huibin "Change of coercivity of magnetic thin film with non-magnetic layers and application to spin valve". J. Magn.Magn. Mater. 268 (2004) 321-325. 20. . . , . . , . . . " Ni-Ge: Ge ". Journal of Siberian Federal University. Mathematics & Physics. 2(3) (2009) 376383. 21. M. Cougo dos Santos, J. Geshev, L. G. Pereira, M. C. M. Alves, J. E. Shmidt. "Intralayer coupling in self-organized Fe nanoclusters grown on vicinal Si(111)" Physical Review B 70 (2004) 104402 22. Qiong Wu, Wei He, Hai-Liang, Jun Ye, Xiang-Qun Zhang, Hai-Tao Yang, Zi-Yu Chen, Zhao-Hua Cheng. "Tuning magnetic anisotropies of Fe films on Si(111) substrate via direction variation of heating current". Scientific Reports. 3 (2013) DOI: 10.1038/srep01547. 23. Yanai T., T. Shimokava, Y. Watanabe, T. Ohgai, M. Nakano, K. Suzuki, H. Fukanaga. "Effect of current density on magnetic properties of electrodeposited Fe-Ni Films prepared in a citric-acid-based-bath." Journal of Applied Physics 115 (2014) 17A325. 24. T.Liu, Y. Zhang, J. W. Cai, H. Y. Pan. "Thermal robust Mo/CoFeB/MgO trilayers with strong perpendicular magnetic anisotropy" Scientific Report. 4 (2014) DOI: 10.1038/srep05895. 25. Guozhi Chai, Nguyen N. Phuoc, C. K. Ong. "Exchange coupling driven omnidirectial rotatable anisotropy in ferrite doped CoFe thin film." Scientific Report. 2 (2012) DOI: 10.1038/srep00832. 26. , . ., , . ., , . ., , . . " FeNi/Bi/FeNi". 11 « ». -- 2 (2008) 105-108. 27. Hsu Jen-Hwa, Sahu D. R. "Interlayer coupling in a trilayer junction having bismuth as spacer layer" Appl. Phys. Lett. 86, (2005) 192501 (4 pages). 28. Wen Li, Michael Fronk, M. Albrecht, M. Franke, Dietrich R. T. Zahn, G. Salvan. "Field-dependent magneto-optical Kerr effect spectroscopy applied to the magnetic component diagnosis of a rubrene/Ni system". Optics Express 22 (2014) 18455. 29. I. Bergenti. A. Riminucci, E. Arisi, M. Murgia, M. Cavallini. "Magnetic properties of Cobalt thin films deposited on soft organic layers" JMMM. 316 (2007) 987989. 30. Shalyguina E.E., Shin Kyung-Ho. "Influence of nonmagnetic layer (Ti, Zr, Pt) on magnetic and magneto-optical properties of Fe/NML bilayers and Fe/NML/Fe trilayers" JMMM. 220 (2000) 167-174.
44


31. Szabo S., Kis-Varga M., Beke D.L., Juhasz R. "Effect of residual strain, grain size Fe impurities on magnetic properties of nanocrystalline Ni (Fe) alloys". JMMM. 215216 (2000) 60-62. 32. Chikazumi S. "Physics of Magnetism." New York­London­Sydney: John Willey&Sons, Inc. 2001. 33. E.E. Shalyguina, M.A. Karsanova, L.V. Kozlovsky //Magnetic and magnetooptical properties of Fe/Ti,Zr,Pt and Fe/Ti,Zr,Pt thin-film structures // Letters in JTP, V.26, N4 (2000) pp. 25-30. 34. Lin C.J., Gorman G.L., Lee C.H., Farrow R.F.C., Marinero E.E., Do H.V., Notarys H. "Magnetic and structural properties of Co/Pt multilayers". J. Magn. Magn. Mater. 93 (1991) 194- 206. 35. Shalyguina E.E., Perepelova E.V, Kozlovskii L., Tamanis E. "Magneto-optical investigation of Co/Mo/Co thin-film systems". J. Magn. Magn. Mater. 300, Issues 1 (2006) e363-e366. 36. ., .., .. " Fe/ /Fe (: ,) ". . 37, 20 (2011) 80-86. 37. . " ". . 42, (2000) 116-120. 38. Coehoorn R. "Period of oscillatory exchange interactions in Co/Cu and Fe/Cu multilayer systems". Phys. Rev. B 44 (1991) 9331-9337. 39. Yafet Y. "Ruderman-Kittel-Kasuya-Yosida range function of a one-dimensional free-electron gas". Phys. Rev. B 36 (1987) 3948-3949. 40. Ortega. M., Himpsel F. "Quantum well states as mediators of magnetic coupling in superlattices". Ph ys. Rev. Lett. 69, (1992) 844-852. 41. Himpsel F. "Magnetic quantum wells" J. Phys.: Condens. Matter 11 (1999) 94839494.

45


, , XXII , «-2015», , ­ « 2015», - 07-12.2015 ., «Magnetism and Optical Research ( )», 29.11-02.12.2015 ., ; . : 1. .. , .. , .. // Co/Bi/Co // XXII , «-2015», . 267 ­ 269. 2. E.E. Shalygina, E.A. Gan'shina, Kharlamova A.M., Doronin D.S., Svalov A.V., Kurlyandskaya G.V. // The Influence of Bi on Magnetic and Magneto-Optical Properties of Co/Bi/Co Low-dimensional Thin-Film Structures // Book of abstarcts of International Symposium "Spin Waves 2015", Ioffe Physical-Technical Institute Saint Petersburg, Russia, , . 133. 3. E.E. Shalygina, A.M. Kharlamova , D.S. Doronin, G.V. Kurlyandskaya, A.V. Svalov // MAGNETO-OPTICAL INVESTIGATIONS OF LOW-DIMENSIONAL THIN-FILM CO/BI/CO SYSTEMS // MORIS 2015, Magnetics and Optics Research International Symposium, Toyohashi University of Technology ­ Universiti Sains Malaysia, , . 33-34.

46


.

., .. , .

., ..

, , , ,

47