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BIBO
BIBO (BiB3O6) is a newly developed nonlinear optical (NLO) crystal, which has excellent characteristics for nonlinear optical applications. BIBO has a broad transparency range, from 286nm to 2500nm, a high optical homogeneity (n10-6cm) and is free of inclusions. BIBO's effective SHG coefficient is about 9 times that of KTP. In addition, BIBO has a high damage threshold, wide temperature bandwidth and inertness with respect to moisture.

Structural and Physical Properties
Crystal Structure Lattice Parameters Melting Point (Congruent) Hardness Specific Heat Thermal Expansion Density Long Term Stability Monoclinic, point group 2 a = 7.116 е, b = 4.993 е, c = 6.508 е 726 oC 5 - 5.5 Mohs 0.5 J/g K at 330 K [X] 48x10-6/K, [Y] 4.4x10-6/K, [Z] ­26.9x10-6/K 5.033 g/cm3 Insensitive to moisture Z = 105.62°

Optical Properties
Transmission range NLO coefficients: Refractive Indices 539.75 nm 1079.5 nm
2

286 - 2500 nm d12 = d14 = 2.3, d25 = d36 = 2.4, d11 = 2.53, d13 = -1.3, d35 = -0.9, d26 = 2.8 pm/V n1 = 1.9620 n1 = 1.9166
2

n2 = 1.7874 n2 = 1.7569
2

n3 = 1.8190 n3 = 1.7835 D 0.0226(1) 0.01337(6) 0.01750(8)

Sellmeier coefficients n n n
1 2 3

A 3.6545(4) 3.0740(3) 3.1685(3)

n (i) = A + B / (i - C) ­ D i B C 0.0511(2) 0.0371(3) 0.0323(1) 0.0316(3) 0.0373(1) 0.0346(3)

Nonlinear Optical Properties Comparisons (SHG at 946nm)
Crystals BIBO LBO BBO Length 10.4 mm 10.0 mm 8.0 mm Deff 3.30 pm/V 0.81 pm/V 2.00 pm/V Walk-off 40.7 mrad 11.3 mrad 60.3 mrad Output Power 2.80 W 1.52 W 2.10 W Conv. Eff. 63% 33% 47%

2370-A Qume Drive, San Jose, CA 95131, Tel: (408) 436-5558, Fax: (408) 436-5557 http://www.forealspectrum.com email: sales@forealspectrum.com BIBONLO, Rev 1.2, 2/13/2006, Page 1/2


BIBO
BIBO Applications
SHG and THG of middle and high power Nd doped lasers at 1064nm. SHG of high power Nd doped lasers at 1342nm and 1319nm for red laser, and THG for blue laser. SHG of the Nd doped lasers at 914nm and 946nm for blue laser. Non-critical phase matched SHG generation over a broad wavelength range, from 900nm to 1700nm. Optical parametric amplifiers (OPA) and oscillators (OPO).

BIBO Specifications
Transmission Wavefront Distortion Dimension Tolerance Flatness Scratch/Dig code Parallelism Perpendicularity Angle tolerance < /8 at 633nm (W: ± 0.1 mm) x (H: ± 0.1 mm) x (L: + 0.2 mm/- 0.1 mm) /8 at 633 nm 10/5 to MIL-O-13830A < 20 arc seconds 5 arc minutes < ± 0.3°, < ± 0.3°

Standard Products
BIBO1305 BIBO1307 BIBO1310 BIBO1410 Dimensions 3 x 3 x 5 mm3 3 x 3 x 7 mm3 3 x 3 x 10 mm3 4 x 4 x 10 mm3 Application SHG or THG SHG or THG SHG or THG SHG or THG Coating AR AR AR AR Type I I I I

Custom high quality BIBO crystals up to 20 x 20 x 40 mm3 are available on request. High damage threshold AR-coating is available. One-year warranty for all products under proper use.

2370-A Qume Drive, San Jose, CA 95131, Tel: (408) 436-5558, Fax: (408) 436-5557 http://www.forealspectrum.com email: sales@forealspectrum.com BIBONLO, Rev 1.2, 2/13/2006, Page 2/2